Jirong Lan , Yan Sun , Huayi Yin , Haobo Hou , Jian-Guo Dai
{"title":"典型散装尾矿中有价金属的可持续电富集回收","authors":"Jirong Lan , Yan Sun , Huayi Yin , Haobo Hou , Jian-Guo Dai","doi":"10.1016/j.watres.2025.123895","DOIUrl":null,"url":null,"abstract":"<div><div>Valuable metal elements (VMEs) are critical components underpinning modern society, yet their extraction generates VME-rich slag and tailings at volumes dozens of times greater than the recovered products. Conventional stockpiling and cement-based landfill strategies pose dual risks: persistent leaching of VMEs into aquatic systems and substantial CO₂ emissions, aggravating global mineral-water resource conflicts. To address this, we developed an electrodynamics-assisted alkali chemistry (EAC) process that synchronizes tailings stabilization with VME recovery. The EAC method leverages electrokinetic migration to enrich VMEs at the cathode during alkali-activated slurry hardening, enabling efficient temporary retention for subsequent metallurgical extraction, while the anode region undergoes rapid consolidation for mine shaft rehabilitation. Validated through lab experiments and scaled field trials, EAC demonstrated a compressive strength enhancement of two orders of magnitude in treated tailings compared to conventional approaches, alongside a 70 % increase in VME recovery efficiency and an 80 % reduction in CO₂ emissions. This study establishes EAC as a transformative, green, and low-carbon technology that concurrently addresses mine restoration, resource circularity, and emission mitigation. By redefining tailings management from waste disposal to value recovery, EAC provides a paradigm shift toward sustainable mining practices, offering critical insights for resolving global resource sustainability challenges.</div></div>","PeriodicalId":443,"journal":{"name":"Water Research","volume":"284 ","pages":"Article 123895"},"PeriodicalIF":11.4000,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sustainable electro-enrichment recovery of valuable metals from typical bulk tailings\",\"authors\":\"Jirong Lan , Yan Sun , Huayi Yin , Haobo Hou , Jian-Guo Dai\",\"doi\":\"10.1016/j.watres.2025.123895\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Valuable metal elements (VMEs) are critical components underpinning modern society, yet their extraction generates VME-rich slag and tailings at volumes dozens of times greater than the recovered products. Conventional stockpiling and cement-based landfill strategies pose dual risks: persistent leaching of VMEs into aquatic systems and substantial CO₂ emissions, aggravating global mineral-water resource conflicts. To address this, we developed an electrodynamics-assisted alkali chemistry (EAC) process that synchronizes tailings stabilization with VME recovery. The EAC method leverages electrokinetic migration to enrich VMEs at the cathode during alkali-activated slurry hardening, enabling efficient temporary retention for subsequent metallurgical extraction, while the anode region undergoes rapid consolidation for mine shaft rehabilitation. Validated through lab experiments and scaled field trials, EAC demonstrated a compressive strength enhancement of two orders of magnitude in treated tailings compared to conventional approaches, alongside a 70 % increase in VME recovery efficiency and an 80 % reduction in CO₂ emissions. This study establishes EAC as a transformative, green, and low-carbon technology that concurrently addresses mine restoration, resource circularity, and emission mitigation. By redefining tailings management from waste disposal to value recovery, EAC provides a paradigm shift toward sustainable mining practices, offering critical insights for resolving global resource sustainability challenges.</div></div>\",\"PeriodicalId\":443,\"journal\":{\"name\":\"Water Research\",\"volume\":\"284 \",\"pages\":\"Article 123895\"},\"PeriodicalIF\":11.4000,\"publicationDate\":\"2025-05-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water Research\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0043135425008036\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water Research","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0043135425008036","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Sustainable electro-enrichment recovery of valuable metals from typical bulk tailings
Valuable metal elements (VMEs) are critical components underpinning modern society, yet their extraction generates VME-rich slag and tailings at volumes dozens of times greater than the recovered products. Conventional stockpiling and cement-based landfill strategies pose dual risks: persistent leaching of VMEs into aquatic systems and substantial CO₂ emissions, aggravating global mineral-water resource conflicts. To address this, we developed an electrodynamics-assisted alkali chemistry (EAC) process that synchronizes tailings stabilization with VME recovery. The EAC method leverages electrokinetic migration to enrich VMEs at the cathode during alkali-activated slurry hardening, enabling efficient temporary retention for subsequent metallurgical extraction, while the anode region undergoes rapid consolidation for mine shaft rehabilitation. Validated through lab experiments and scaled field trials, EAC demonstrated a compressive strength enhancement of two orders of magnitude in treated tailings compared to conventional approaches, alongside a 70 % increase in VME recovery efficiency and an 80 % reduction in CO₂ emissions. This study establishes EAC as a transformative, green, and low-carbon technology that concurrently addresses mine restoration, resource circularity, and emission mitigation. By redefining tailings management from waste disposal to value recovery, EAC provides a paradigm shift toward sustainable mining practices, offering critical insights for resolving global resource sustainability challenges.
期刊介绍:
Water Research, along with its open access companion journal Water Research X, serves as a platform for publishing original research papers covering various aspects of the science and technology related to the anthropogenic water cycle, water quality, and its management worldwide. The audience targeted by the journal comprises biologists, chemical engineers, chemists, civil engineers, environmental engineers, limnologists, and microbiologists. The scope of the journal include:
•Treatment processes for water and wastewaters (municipal, agricultural, industrial, and on-site treatment), including resource recovery and residuals management;
•Urban hydrology including sewer systems, stormwater management, and green infrastructure;
•Drinking water treatment and distribution;
•Potable and non-potable water reuse;
•Sanitation, public health, and risk assessment;
•Anaerobic digestion, solid and hazardous waste management, including source characterization and the effects and control of leachates and gaseous emissions;
•Contaminants (chemical, microbial, anthropogenic particles such as nanoparticles or microplastics) and related water quality sensing, monitoring, fate, and assessment;
•Anthropogenic impacts on inland, tidal, coastal and urban waters, focusing on surface and ground waters, and point and non-point sources of pollution;
•Environmental restoration, linked to surface water, groundwater and groundwater remediation;
•Analysis of the interfaces between sediments and water, and between water and atmosphere, focusing specifically on anthropogenic impacts;
•Mathematical modelling, systems analysis, machine learning, and beneficial use of big data related to the anthropogenic water cycle;
•Socio-economic, policy, and regulations studies.