典型散装尾矿中有价金属的可持续电富集回收

IF 11.4 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL
Jirong Lan , Yan Sun , Huayi Yin , Haobo Hou , Jian-Guo Dai
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引用次数: 0

摘要

有价金属元素(VMEs)是支撑现代社会的重要组成部分,但它们的开采产生的富含vme的矿渣和尾矿的数量是回收产品的数十倍。传统的储存和以水泥为基础的垃圾填埋策略存在双重风险:VMEs持续渗入水生系统和大量二氧化碳排放,加剧全球矿泉水资源冲突。为了解决这个问题,我们开发了一种电动力学辅助碱化学(EAC)工艺,该工艺可以同步尾矿稳定和VME回收。EAC方法在碱活化浆液硬化过程中利用电动迁移富集阴极的vme,为后续的冶金提取提供有效的临时保留,而阳极区域则进行快速固结,用于矿井修复。经过实验室实验和规模现场试验的验证,与传统方法相比,EAC处理后的尾矿的抗压强度提高了两个数量级,同时VME回收效率提高了70%,二氧化碳排放量减少了80%。本研究将EAC确立为一种变革性、绿色和低碳技术,同时解决矿山恢复、资源循环和减排问题。通过将尾矿管理从废物处理重新定义为价值回收,EAC提供了向可持续采矿实践的范式转变,为解决全球资源可持续性挑战提供了关键见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Sustainable electro-enrichment recovery of valuable metals from typical bulk tailings
Valuable metal elements (VMEs) are critical components underpinning modern society, yet their extraction generates VME-rich slag and tailings at volumes dozens of times greater than the recovered products. Conventional stockpiling and cement-based landfill strategies pose dual risks: persistent leaching of VMEs into aquatic systems and substantial CO₂ emissions, aggravating global mineral-water resource conflicts. To address this, we developed an electrodynamics-assisted alkali chemistry (EAC) process that synchronizes tailings stabilization with VME recovery. The EAC method leverages electrokinetic migration to enrich VMEs at the cathode during alkali-activated slurry hardening, enabling efficient temporary retention for subsequent metallurgical extraction, while the anode region undergoes rapid consolidation for mine shaft rehabilitation. Validated through lab experiments and scaled field trials, EAC demonstrated a compressive strength enhancement of two orders of magnitude in treated tailings compared to conventional approaches, alongside a 70 % increase in VME recovery efficiency and an 80 % reduction in CO₂ emissions. This study establishes EAC as a transformative, green, and low-carbon technology that concurrently addresses mine restoration, resource circularity, and emission mitigation. By redefining tailings management from waste disposal to value recovery, EAC provides a paradigm shift toward sustainable mining practices, offering critical insights for resolving global resource sustainability challenges.
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来源期刊
Water Research
Water Research 环境科学-工程:环境
CiteScore
20.80
自引率
9.40%
发文量
1307
审稿时长
38 days
期刊介绍: Water Research, along with its open access companion journal Water Research X, serves as a platform for publishing original research papers covering various aspects of the science and technology related to the anthropogenic water cycle, water quality, and its management worldwide. The audience targeted by the journal comprises biologists, chemical engineers, chemists, civil engineers, environmental engineers, limnologists, and microbiologists. The scope of the journal include: •Treatment processes for water and wastewaters (municipal, agricultural, industrial, and on-site treatment), including resource recovery and residuals management; •Urban hydrology including sewer systems, stormwater management, and green infrastructure; •Drinking water treatment and distribution; •Potable and non-potable water reuse; •Sanitation, public health, and risk assessment; •Anaerobic digestion, solid and hazardous waste management, including source characterization and the effects and control of leachates and gaseous emissions; •Contaminants (chemical, microbial, anthropogenic particles such as nanoparticles or microplastics) and related water quality sensing, monitoring, fate, and assessment; •Anthropogenic impacts on inland, tidal, coastal and urban waters, focusing on surface and ground waters, and point and non-point sources of pollution; •Environmental restoration, linked to surface water, groundwater and groundwater remediation; •Analysis of the interfaces between sediments and water, and between water and atmosphere, focusing specifically on anthropogenic impacts; •Mathematical modelling, systems analysis, machine learning, and beneficial use of big data related to the anthropogenic water cycle; •Socio-economic, policy, and regulations studies.
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