邻苯桥接Al/P对对小分子的反应性

IF 2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2025-04-07 DOI:10.1002/ejic.202500174

Melina E. A. Dilanas, Frank Breher

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引用次数: 0

摘要

受挫刘易斯对（FLPs）作为两亲性分子容易激活小分子，多年来一直是人们关注的焦点。本文首次提出了邻苯二烯桥接的仅含一个膦基团的Al/ p基FLP。标题化合物用于与具有不同官能团的小分子的各种反应中。Al/ p基FLP容易形成加合物或活化产物，并能在室温下可逆活化CO2。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Reactivity of an Ortho-Phenylene-Bridged Al/P Frustrated Lewis Pair toward Small Molecules

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Reactivity of an Ortho-Phenylene-Bridged Al/P Frustrated Lewis Pair toward Small Molecules

Frustrated Lewis pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. Herein, the first ortho-phenylene-bridged Al/P-based FLP with only one phosphine moiety is presented. The title compound is employed in various reactions with small molecules featuring different functional groups. The Al/P-based FLP readily forms adducts or activation products and can reversibly activate CO₂ at room temperature.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.