Anthony Ranaivoniriana, Ahmed Ben Akouche, Axel Desnoyers de Marbaix, Daniel Rose, Yaovi Holade, Boniface Kokoh, Dodzi Zigah, Karine Servat, Teko Napporn, Sylvain Argentieri, Emmanuel Maisonhaute
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Upcycling old hard drives into polishing machines and rotating disk electrodes
Following technological evolutions, commercial electrochemical devices are now very compact, but often hard to repair, so that we observe an increase of open-source electrochemical hardware. In this paper, we exploit the former hard drive technology to recycle the brushless motor in order to build a polishing machine and a rotating disk electrode (RDE). Each step of the construction is detailed. The RDE performance is evaluated by linear sweep voltammetry of the classical ferrocenedimethanol redox system. Quantification thanks to the Levich equation provides a diffusion coefficient of ferrocenedimethanol of (4.6 ± 1) × 10−10 m2 s−1 in aqueous potassium chloride electrolyte, which is close to the literature, thus validating home-made RDE. Using these devices with the PassStat, an open-source potentiostat allows to build an electrochemical set-up at a very reduced price (less than 150 € for the three devices). The approach will be of specific interest for teaching instrumentation and for countries of lower resources.
期刊介绍:
The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry.
The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces.
The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis.
The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.