{"title":"用交联剂生物合成Ag-SiO2杂化纳米流体增强棉织物的多功能和力学性能","authors":"Mst. Tania Aktek, Mohammad Ali","doi":"10.1007/s10570-025-06520-z","DOIUrl":null,"url":null,"abstract":"<div><p>The utilization of agro waste in the green synthesis of nanoparticles (NPs) is recognized as one of the most environment benign and cost-effective approaches. Accordingly, the present study biosynthesizes Ag and SiO<sub>2</sub> NPs by utilizing agro waste, lemon peel zest and rice husks to produce two hybrid nano fluids named Ag–SiO<sub>2</sub> and Ag–SiO<sub>2</sub>–bis for the purpose of yielding mechanically strong, durable, functional and comfortable cotton fabric. The synthesized nano fluids are incorporated on cotton woven fabric by mechanical thermo-fixation method. The produced Ag NPs are characterized by UV–visible spectroscopy, Field Emission Electron Microscopy (FESEM) and Energy Dispersive Spectroscopy (EDX), and found the average size as around 30 nm with spherical shape. Again, SiO<sub>2</sub> NPs are characterized by Fourier Transform Infrared Spectroscopy (FTIR), FESEM and EDX and the results reveal amorphous, spherical shape with the average particle size as around 50 nm. The FESEM of hybrid NPs are also analyzed. The surface morphology of treated fabric is assessed by SEM (Scanning Electron Microscopy) and EDX. The antibacterial properties, UV protection ability, dye ability, moisture management property, mechanical properties are assessed and found better than that of untreated fabric. However, due to use of small amount of the above NPs in preparation of hybrid nano fluid, UV-protection ability is not found up to the mark. For addressing the durability of the functional cotton fabric, N, N′-methylene bis-acrylamide is used as a crosslinking agent which has also significant positive contribution to mechanical properties. However, this utilization of the cross-linker along with Ag–SiO<sub>2</sub> hybrid nano fluid is the novelty of present investigation to improve the durable, functional and mechanical properties. The outcomes of the study suggest the greater efficacy of Ag–SiO<sub>2</sub>–bis hybrid nano fluid in functional clothing and medical textiles.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 7","pages":"4615 - 4633"},"PeriodicalIF":4.8000,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Biosynthesized Ag–SiO2 hybrid nano fluid with cross-linker for augmentation of multifunctional and mechanical properties of cotton fabric\",\"authors\":\"Mst. Tania Aktek, Mohammad Ali\",\"doi\":\"10.1007/s10570-025-06520-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The utilization of agro waste in the green synthesis of nanoparticles (NPs) is recognized as one of the most environment benign and cost-effective approaches. Accordingly, the present study biosynthesizes Ag and SiO<sub>2</sub> NPs by utilizing agro waste, lemon peel zest and rice husks to produce two hybrid nano fluids named Ag–SiO<sub>2</sub> and Ag–SiO<sub>2</sub>–bis for the purpose of yielding mechanically strong, durable, functional and comfortable cotton fabric. The synthesized nano fluids are incorporated on cotton woven fabric by mechanical thermo-fixation method. The produced Ag NPs are characterized by UV–visible spectroscopy, Field Emission Electron Microscopy (FESEM) and Energy Dispersive Spectroscopy (EDX), and found the average size as around 30 nm with spherical shape. Again, SiO<sub>2</sub> NPs are characterized by Fourier Transform Infrared Spectroscopy (FTIR), FESEM and EDX and the results reveal amorphous, spherical shape with the average particle size as around 50 nm. The FESEM of hybrid NPs are also analyzed. The surface morphology of treated fabric is assessed by SEM (Scanning Electron Microscopy) and EDX. The antibacterial properties, UV protection ability, dye ability, moisture management property, mechanical properties are assessed and found better than that of untreated fabric. However, due to use of small amount of the above NPs in preparation of hybrid nano fluid, UV-protection ability is not found up to the mark. For addressing the durability of the functional cotton fabric, N, N′-methylene bis-acrylamide is used as a crosslinking agent which has also significant positive contribution to mechanical properties. However, this utilization of the cross-linker along with Ag–SiO<sub>2</sub> hybrid nano fluid is the novelty of present investigation to improve the durable, functional and mechanical properties. The outcomes of the study suggest the greater efficacy of Ag–SiO<sub>2</sub>–bis hybrid nano fluid in functional clothing and medical textiles.</p></div>\",\"PeriodicalId\":511,\"journal\":{\"name\":\"Cellulose\",\"volume\":\"32 7\",\"pages\":\"4615 - 4633\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-04-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Cellulose\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10570-025-06520-z\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, PAPER & WOOD\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Cellulose","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10570-025-06520-z","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, PAPER & WOOD","Score":null,"Total":0}
Biosynthesized Ag–SiO2 hybrid nano fluid with cross-linker for augmentation of multifunctional and mechanical properties of cotton fabric
The utilization of agro waste in the green synthesis of nanoparticles (NPs) is recognized as one of the most environment benign and cost-effective approaches. Accordingly, the present study biosynthesizes Ag and SiO2 NPs by utilizing agro waste, lemon peel zest and rice husks to produce two hybrid nano fluids named Ag–SiO2 and Ag–SiO2–bis for the purpose of yielding mechanically strong, durable, functional and comfortable cotton fabric. The synthesized nano fluids are incorporated on cotton woven fabric by mechanical thermo-fixation method. The produced Ag NPs are characterized by UV–visible spectroscopy, Field Emission Electron Microscopy (FESEM) and Energy Dispersive Spectroscopy (EDX), and found the average size as around 30 nm with spherical shape. Again, SiO2 NPs are characterized by Fourier Transform Infrared Spectroscopy (FTIR), FESEM and EDX and the results reveal amorphous, spherical shape with the average particle size as around 50 nm. The FESEM of hybrid NPs are also analyzed. The surface morphology of treated fabric is assessed by SEM (Scanning Electron Microscopy) and EDX. The antibacterial properties, UV protection ability, dye ability, moisture management property, mechanical properties are assessed and found better than that of untreated fabric. However, due to use of small amount of the above NPs in preparation of hybrid nano fluid, UV-protection ability is not found up to the mark. For addressing the durability of the functional cotton fabric, N, N′-methylene bis-acrylamide is used as a crosslinking agent which has also significant positive contribution to mechanical properties. However, this utilization of the cross-linker along with Ag–SiO2 hybrid nano fluid is the novelty of present investigation to improve the durable, functional and mechanical properties. The outcomes of the study suggest the greater efficacy of Ag–SiO2–bis hybrid nano fluid in functional clothing and medical textiles.
期刊介绍：
Cellulose is an international journal devoted to the dissemination of research and scientific and technological progress in the field of cellulose and related naturally occurring polymers. The journal is concerned with the pure and applied science of cellulose and related materials, and also with the development of relevant new technologies. This includes the chemistry, biochemistry, physics and materials science of cellulose and its sources, including wood and other biomass resources, and their derivatives. Coverage extends to the conversion of these polymers and resources into manufactured goods, such as pulp, paper, textiles, and manufactured as well natural fibers, and to the chemistry of materials used in their processing. Cellulose publishes review articles, research papers, and technical notes.
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