阿拉伯盾中含锂伟晶岩的形成:以沙特阿拉伯阿西尔特兰的阿布拉山为例

IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES
Mokhles K. Azer, Hisham A. Gahlan, Omar Bartoli
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引用次数: 0

摘要

目前,沙特阿拉伯没有锂开采活动,尽管阿拉伯地盾富含适合经济富集锂的岩石,包括伟晶岩、灰色和稀有金属花岗岩,以及古老的盐水和盐矿床。目前的工作是第一次报道锂云母,这是一种主要的含锂矿物,位于阿西尔地系Ablah地本北部的Ablah伟晶岩山。伟晶岩是亚伯拉山的主要岩石类型,其边缘角化作用强烈,周围为绢云母岩蚀变带,并被许多石英脉交叉切割。它们也被一个巨大的白云母-萤石体所覆盖,在这里被称为灰岩矿床。研究的伟晶岩为中粗粒伟晶岩,可分为含云母伟晶岩和无云母伟晶岩两类。含绢云母伟晶岩由钾长石、白云母、石英和绢云母组成,无绢云母伟晶岩由钾长石和石英组成。萤石、锡石、黄玉、电气石和绿柱石是主要的辅助矿物。锂云石的晶体形状为半面体或半面体,颜色从粉红色到紫色不等。地球化学特征为Mg、Ca、Ba、Sr含量低,碱性元素Sn (870 ~ 1205 ppm)、Ta (34 ~ 61 ppm)、Nb (351 ~ 469 ppm)、Y (130 ~ 165 ppm)、Rb (166 ~ 2606 ppm)、Cs (265 ~ 357 ppm)、Li (4727 ~ 7865 ppm)、Be (309 ~ 597 ppm)含量高。这些成分特征是典型的碰撞后、含稀有金属的混合NYF-LCT类伟晶岩。所有辉化岩样品均呈现正Ta异常和明显的负Eu异常(Eu/Eu* = 0.14 ~ 0.21)。我们认为,亚伯拉山伟晶岩的源岩浆主要来自于阿拉伯盾的幼年大陆地壳的部分熔融作用,可能是在乌姆法瓦主剪切带演化过程中形成的。在热液后期,富f流体的析出输送了一些元素,并在局部将它们的浓度提高到经济等级。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Formation of Li-bearing pegmatites in the Arabian Shield: A case study from the Mount Ablah, Asir Terran, Saudi Arabia

There is currently no lithium mining activity in Saudi Arabia, although the Arabian Shield is rich in rocks suitable for economic concentrations of lithium, including pegmatites, greisen and rare metal granites, as well as ancient brines and salt deposits. The present work is the first to report lepidolite, the major lithium-bearing mineral, hosted by the Mount Ablah pegmatite, located north of the Ablah Graben, Asir Terrane. The pegmatitic rocks represent the dominant rock types in the Mount Ablah, where they are strongly brecciated along the margins and surrounded by alteration zone of sericitized rocks, and cross-cut by a number of quartz veins. They are also covered by a massive muscovite-fluorite body, here described as a greisen deposit. The studied pegmatites are medium- to coarse-grained and are of two types: lepidolite-bearing and lepidolite-absent pegmatites. The lepidolite-bearing pegmatite consists of K-feldspar, muscovite, quartz and lepidolite, whereas the lepidolite-absent pegmatite consists of K-feldspar and quartz. Fluorite, cassiterite, topaz, tourmaline and beryl are the main accessory minerals. The lepidolite forms crystals of anhedral to subhedral shapes and clusters and varies in colour from pink to purple. Geochemically, the Ablah pegmatite is characterized by low amounts of Mg, Ca, Ba and Sr, but high contents of alkaline elements, Sn (870–1205 ppm), Ta (34–61 ppm), Nb (351–469 ppm), Y (130–165 ppm), Rb (1916–2606 ppm), Cs (265–357 ppm), Li (4727–7865 ppm) and Be (309-597 ppm). These compositional features are typical of post-collisional, rare metal-bearing pegmatites of the mixed NYF-LCT family. All pegmatitic samples show positive Ta anomalies and distinct negative Eu anomalies (Eu/Eu* = 0.14–0.21). We suggest that the source magma of the pegmatitic rocks of Mount Ablah was mostly derived from the juvenile continental crust of the Arabian Shield through partial melting, probably during the evolution of the major Shear Zone of Umm Farwah. The anatectic crustal melts were subsequently subjected to a high degree of fractional crystallization and during the latter hydrothermal stage the exsolution of F-rich fluids transported some elements and locally increased their concentrations to economic grades.

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来源期刊
Environmental Earth Sciences
Environmental Earth Sciences 环境科学-地球科学综合
CiteScore
5.10
自引率
3.60%
发文量
494
审稿时长
8.3 months
期刊介绍: Environmental Earth Sciences is an international multidisciplinary journal concerned with all aspects of interaction between humans, natural resources, ecosystems, special climates or unique geographic zones, and the earth: Water and soil contamination caused by waste management and disposal practices Environmental problems associated with transportation by land, air, or water Geological processes that may impact biosystems or humans Man-made or naturally occurring geological or hydrological hazards Environmental problems associated with the recovery of materials from the earth Environmental problems caused by extraction of minerals, coal, and ores, as well as oil and gas, water and alternative energy sources Environmental impacts of exploration and recultivation – Environmental impacts of hazardous materials Management of environmental data and information in data banks and information systems Dissemination of knowledge on techniques, methods, approaches and experiences to improve and remediate the environment In pursuit of these topics, the geoscientific disciplines are invited to contribute their knowledge and experience. Major disciplines include: hydrogeology, hydrochemistry, geochemistry, geophysics, engineering geology, remediation science, natural resources management, environmental climatology and biota, environmental geography, soil science and geomicrobiology.
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