铝的力量:优化金属间化合物Eu5+xAl3+ySb6的热电性能。

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Luis Garay , Leah Borgsmiller , G. Jeffrey Snyder , Susan M. Kauzlarich
{"title":"铝的力量:优化金属间化合物Eu5+xAl3+ySb6的热电性能。","authors":"Luis Garay ,&nbsp;Leah Borgsmiller ,&nbsp;G. Jeffrey Snyder ,&nbsp;Susan M. Kauzlarich","doi":"10.1039/d5cc01165e","DOIUrl":null,"url":null,"abstract":"<div><div>Eu<sub>5.08</sub>Al<sub>3</sub>Sb<sub>6</sub> can be described as a pseudo rock salt-like “(Eu/Al<sub>4</sub>)Sb” structure. The polycrystalline synthesis of Eu<sub>5+<em>x</em></sub>Al<sub>3+<em>y</em></sub>Sb<sub>6</sub> was optimized. The compositions exhibit n-type transport behavior, ultra-low thermal conductivity, and a high Seebeck coefficient. Eu<sub>5.08</sub>Al<sub>4</sub>Sb<sub>6</sub> shows a promising <em>zT</em> of 0.8 at a temperature of 873 K.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 50","pages":"Pages 9071-9074"},"PeriodicalIF":4.2000,"publicationDate":"2025-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The power of aluminum: optimizing thermoelectric properties of the intermetallic, Eu5+xAl3+ySb6†\",\"authors\":\"Luis Garay ,&nbsp;Leah Borgsmiller ,&nbsp;G. Jeffrey Snyder ,&nbsp;Susan M. Kauzlarich\",\"doi\":\"10.1039/d5cc01165e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Eu<sub>5.08</sub>Al<sub>3</sub>Sb<sub>6</sub> can be described as a pseudo rock salt-like “(Eu/Al<sub>4</sub>)Sb” structure. The polycrystalline synthesis of Eu<sub>5+<em>x</em></sub>Al<sub>3+<em>y</em></sub>Sb<sub>6</sub> was optimized. The compositions exhibit n-type transport behavior, ultra-low thermal conductivity, and a high Seebeck coefficient. Eu<sub>5.08</sub>Al<sub>4</sub>Sb<sub>6</sub> shows a promising <em>zT</em> of 0.8 at a temperature of 873 K.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 50\",\"pages\":\"Pages 9071-9074\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-06-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734525010493\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525010493","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

Eu5.08Al3Sb6可以描述为一种伪岩盐状的“(Eu/Al4)Sb”结构。优化了Eu5+xAl3+ySb6的多晶合成工艺。该组合物表现出n型输运行为、超低导热系数和高塞贝克系数。在873 K温度下,Eu5.08Al4Sb6的zT为0.8。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The power of aluminum: optimizing thermoelectric properties of the intermetallic, Eu5+xAl3+ySb6†
Eu5.08Al3Sb6 can be described as a pseudo rock salt-like “(Eu/Al4)Sb” structure. The polycrystalline synthesis of Eu5+xAl3+ySb6 was optimized. The compositions exhibit n-type transport behavior, ultra-low thermal conductivity, and a high Seebeck coefficient. Eu5.08Al4Sb6 shows a promising zT of 0.8 at a temperature of 873 K.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信