在生物相容性溶液中激光烧蚀月桂叶合成高荧光碳点

IF 3.2 4区 化学 Q2 CHEMISTRY, ANALYTICAL
Luminescence Pub Date : 2025-05-23 DOI:10.1002/bio.70202
L. Torrisi, M. Cutroneo, A. Torrisi, D. Manno, A. Serra
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引用次数: 0

摘要

用激光照射月桂叶,可得到绿色碳点(CDs)。CDs的合成是用Nd:YAG激光照射放置在磷酸盐缓冲盐水(PBS)溶液中的多层叶片得到的。溶液盐生成纳米粒子及其功能化在可见光区产生高强度的色散发光,这是由紫外激发引起的。消融使用100兆焦耳能量的ns脉冲,以1赫兹的重复频率聚焦于植物目标。等离子体研究,紫外-可见和红外光谱被采用。提出并讨论了色散的形态、光学性质和其他特性。合成的CDs在274 nm处有一个吸收峰,证实了碳芯态的p-p *跃迁,而CD颗粒呈球形,尺寸小于10 nm。当激发波长为365 nm时,CDs荧光发射在472 nm左右的蓝色区域。合成的CDs在长时间(3个月)内表现出稳定性。该研究提供了一种廉价、绿色、简单的合成CDs的方法,在不同的科学领域,特别是从生物学到医学的重要生物相容性分散体应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of High Fluorescent Carbon Dots by Laser Ablation of Bay Leaves in Biocompatible Solutions

A green dispersion of carbon dots (CDs) can be obtained by laser irradiation of bay leaves in liquids. The CDs synthesis is obtained using an Nd:YAG laser irradiating multilayered leaves placed into a phosphate-buffered saline (PBS) solution. The nanoparticle generation and their functionalization by the solution salts produce a high-intensity dispersion luminescence in the visible region, which is induced by UV excitation. The ablation uses ns pulses with 100 mJ energy employed with a 1 Hz repetition rate focused on the vegetal target. Plasma investigations, UV–visible, and IR optical spectroscopies were employed. Morphological, optical properties, and other characteristics of the dispersion are presented and discussed. The synthesized CDs showed an absorption peak at 274 nm to confirm the p–p* transition of the carbon core state, while the CD particles were spherical with a size of less than 10 nm. The CDs fluorescent emission is in the blue region, around 472 nm, upon excitation at 365 nm. The synthesized CDs showed stability over a long period (3 months). This study provides an inexpensive, green, and simple method for CDs synthesis for important biocompatible dispersion applications in different scientific fields, especially from biology to medicine.

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来源期刊
Luminescence
Luminescence 生物-生化与分子生物学
CiteScore
5.10
自引率
13.80%
发文量
248
审稿时长
3.5 months
期刊介绍: Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry. Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.
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