用冷喷涂技术研究可再加工玻璃体组分金属化的可行性

IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Alessia Serena Perna, Antonello Astarita, Alfonso Martone, Barbara Palmieri, Antonio Viscusi
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引用次数: 0

摘要

环氧玻璃聚合物,以其独特的热固性机械强度与热塑性塑料的可再加工性的结合而闻名,代表了一类有前途的先进技术应用材料。为了优化其在高要求环境下的性能,玻璃体和玻璃体复合材料的表面功能化对于提高其在恶劣条件下的耐久性和可靠性至关重要。本研究工作旨在研究通过冷喷涂技术将玻璃体基组件金属化的可行性。在不同的工艺参数、进口气体温度(T = 150 -450°C)和距离(SoD = 70 mm - 100 mm)下应用铝涂层,以评估它们对沉积质量和衬底行为的影响。沉积过程分别在非增强玻璃体基板和碳纤维增强玻璃体基板上进行。结果表明,当衬底温度超过拓扑冻结转变温度(Tv≈170°C)时,成功的金属化发生,从而实现有效粘附所需的延展性行为。当温度为300°C, SoD为100 mm时,纯玻璃体涂层的平均厚度为50±10µm,基底变形最小(沟槽占面板厚度的4%),而较低温度(T = 150°C)导致脆性断裂,附着力差。表面粗糙度从未涂覆时的Sa = 0.15±0.05µm增加到涂覆后的Sa = 6.59µm。相比之下,由于纤维增强,复合基材表现出增强的稳定性,这限制了过度的基材流动。在最佳工艺条件下(T = 300°C, SoD = 100 mm),复合板获得均匀涂层,Sa = 4.513µm。然而,过高的温度(T = 450°C)会导致纯玻璃钢和复合材料板的基材侵蚀和纤维损坏。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigating the Feasibility of Metallizing Reprocessable Vitrimeric Components through Cold Spray Technique

Epoxy vitrimers, distinguished by their unique combination of the mechanical strength typical of thermosets with the reprocessability of thermoplastics, represent a promising class of materials for advanced technological applications. To optimize their performance in high-demand environments, surface functionalization of vitrimers and vitrimeric composites is crucial to enhance their durability and reliability in harsh conditions. This research work aims at studying the feasibility of metallising vitrimer-based components through cold spray technology. Aluminium coatings were applied under varying process parameters, inlet gas temperature (T = 150 –450 °C) and standoff distance (SoD = 70 mm–100 mm), to evaluate their impact on deposition quality and substrate behaviour. The deposition processes were performed on non-reinforced vitrimeric substrates as well as on vitrimeric matrix substrates reinforced with carbon fibre fabric. The results suggest that successful metallization occurs when the substrate temperature exceeds the topology freezing transition temperature (Tv ≈ 170 °C), enabling the ductile behaviour necessary for effective adhesion. At T = 300 °C and SoD = 100 mm, pure vitrimer coatings exhibited an average thickness of 50 ± 10 µm with minimal substrate deformation (grooves < 4% of panel thickness), while lower temperatures (T = 150 °C) resulted in brittle fracture and poor adhesion. Surface roughness increased from Sa = 0.15 ± 0.05 µm for uncoated substrates to Sa = 6.59 µm after coating. In contrast, composite substrates demonstrated enhanced stability due to fibre reinforcement, which constrained excessive substrate flow. At the best process conditions (T = 300 °C and SoD = 100 mm), composite panels achieved homogeneous coatings with Sa = 4.513 µm. However, excessive temperatures (T = 450 °C) led to substrate erosion and fibre damage in both pure vitrimer and composite panels.

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来源期刊
Journal of Materials Engineering and Performance
Journal of Materials Engineering and Performance 工程技术-材料科学:综合
CiteScore
3.90
自引率
13.00%
发文量
1120
审稿时长
4.9 months
期刊介绍: ASM International''s Journal of Materials Engineering and Performance focuses on solving day-to-day engineering challenges, particularly those involving components for larger systems. The journal presents a clear understanding of relationships between materials selection, processing, applications and performance. The Journal of Materials Engineering covers all aspects of materials selection, design, processing, characterization and evaluation, including how to improve materials properties through processes and process control of casting, forming, heat treating, surface modification and coating, and fabrication. Testing and characterization (including mechanical and physical tests, NDE, metallography, failure analysis, corrosion resistance, chemical analysis, surface characterization, and microanalysis of surfaces, features and fractures), and industrial performance measurement are also covered
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