CuO/ZnO/ZnFe2O4光催化乙醇胺溶液中硫化氢(H2S)的分解

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL
Rania Farouq, Agid Remadan, Nasser A. M. Barakat, Haidar Saify Nabiabad, A. M. Dorgham
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引用次数: 0

摘要

炼油厂产生大量的H2S,它可以在众所周知的克劳斯过程中分解成硫和水。由于昂贵的化学过程和额外的严重的环境问题,它引起的,这种方法是不可行的商业。因此,在这里,我们展示了如何使用光催化降解有毒的H2S,这是一种绿色,非常规的能源,也是环保的。在本研究中,在叙利亚“瑞典天然气厂”对装载H2S的二乙醇胺溶液(DEA)样品进行了实验室实验。研究了纳米CuO/ZnO/ZnFe2O4光催化剂对H2S的降解作用。采用x射线衍射(XRD)、能量色散x射线能谱(EDX或EDS)、扫描电镜(SEM)和透射电镜(TEM)对新制备的CuO/ZnO/ ZnFe2O4的微观结构进行了表征。考察了pH和催化剂用量对光催化剂性能的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Photocatalysis Decomposition of Hydrogen Sulfide (H2S) in Ethanolamine Solution Using CuO/ZnO/ZnFe2O4

Refineries produce large amounts of H2S, which can be decomposed in the well-known Claus process to turn into sulfur and water. Due to the expensive chemical process and additional serious environmental issues, it causes, this approach is not commercially viable. Therefore, herein we have shown how to degrade toxic H2S using phocatalysis, a green, non-conventional energy source that is also environmentally friendly. In this research, laboratory experiments were conducted on a sample of diethanolamine solution (DEA) loaded with H2S from gas associated with oil at “the Swedish Gas Plant” in Syria. We have investigated the use of nanostructured CuO/ZnO/ZnFe2O4 photocatalyst for the degradation of H2S. The microstructure of the newly prepared CuO/ZnO/ ZnFe2O4 was examined using X-ray diffraction (XRD), Energy-Dispersive X-ray Spectroscopy (EDX or EDS), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The effect of pH and catalyst dosage was investigated on the photocatalyst performance.

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来源期刊
Catalysis Letters
Catalysis Letters 化学-物理化学
CiteScore
5.70
自引率
3.60%
发文量
327
审稿时长
1 months
期刊介绍: Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.
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