{"title":"臭氧处理对碳纤维微波加热性能的影响","authors":"Zhihai Huang , Hisahiro Einaga","doi":"10.1016/j.cattod.2025.115386","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, pitch-based carbon fibers were subjected to ozone treatment, resulting in carbon fibers with enhanced microwave heating performance. The alterations in the surface functional groups of the carbon fiber samples were characterized using XPS and FTIR. Changes in the sample surface area and pore distribution were determined based on the nitrogen adsorption isotherms at 77 K. Raman spectroscopy was used to identify variations in the mechanical structure of the samples. Furthermore, an analysis of the electromagnetic field dependence of carbon fiber microwave heating demonstrated that the primary contributing factor for microwave heating in carbon fibers is their high dielectric loss characteristics. In addition, ozone treatment influenced the dielectric loss of the carbon material. The ozone-treated carbon fibers exhibited enhanced microwave heating performance and superior heating reproducibility. This study provides substantive insights into the concurrent utilization of the multifaceted properties of carbon fibers to engineer microwave absorbers with enhanced efficiency and augmented heat conversion capabilities.</div></div>","PeriodicalId":264,"journal":{"name":"Catalysis Today","volume":"458 ","pages":"Article 115386"},"PeriodicalIF":5.2000,"publicationDate":"2025-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of ozone treatment on microwave heating properties of carbon fiber\",\"authors\":\"Zhihai Huang , Hisahiro Einaga\",\"doi\":\"10.1016/j.cattod.2025.115386\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this study, pitch-based carbon fibers were subjected to ozone treatment, resulting in carbon fibers with enhanced microwave heating performance. The alterations in the surface functional groups of the carbon fiber samples were characterized using XPS and FTIR. Changes in the sample surface area and pore distribution were determined based on the nitrogen adsorption isotherms at 77 K. Raman spectroscopy was used to identify variations in the mechanical structure of the samples. Furthermore, an analysis of the electromagnetic field dependence of carbon fiber microwave heating demonstrated that the primary contributing factor for microwave heating in carbon fibers is their high dielectric loss characteristics. In addition, ozone treatment influenced the dielectric loss of the carbon material. The ozone-treated carbon fibers exhibited enhanced microwave heating performance and superior heating reproducibility. This study provides substantive insights into the concurrent utilization of the multifaceted properties of carbon fibers to engineer microwave absorbers with enhanced efficiency and augmented heat conversion capabilities.</div></div>\",\"PeriodicalId\":264,\"journal\":{\"name\":\"Catalysis Today\",\"volume\":\"458 \",\"pages\":\"Article 115386\"},\"PeriodicalIF\":5.2000,\"publicationDate\":\"2025-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Today\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0920586125002044\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Today","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0920586125002044","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Effect of ozone treatment on microwave heating properties of carbon fiber
In this study, pitch-based carbon fibers were subjected to ozone treatment, resulting in carbon fibers with enhanced microwave heating performance. The alterations in the surface functional groups of the carbon fiber samples were characterized using XPS and FTIR. Changes in the sample surface area and pore distribution were determined based on the nitrogen adsorption isotherms at 77 K. Raman spectroscopy was used to identify variations in the mechanical structure of the samples. Furthermore, an analysis of the electromagnetic field dependence of carbon fiber microwave heating demonstrated that the primary contributing factor for microwave heating in carbon fibers is their high dielectric loss characteristics. In addition, ozone treatment influenced the dielectric loss of the carbon material. The ozone-treated carbon fibers exhibited enhanced microwave heating performance and superior heating reproducibility. This study provides substantive insights into the concurrent utilization of the multifaceted properties of carbon fibers to engineer microwave absorbers with enhanced efficiency and augmented heat conversion capabilities.
期刊介绍:
Catalysis Today focuses on the rapid publication of original invited papers devoted to currently important topics in catalysis and related subjects. The journal only publishes special issues (Proposing a Catalysis Today Special Issue), each of which is supervised by Guest Editors who recruit individual papers and oversee the peer review process. Catalysis Today offers researchers in the field of catalysis in-depth overviews of topical issues.
Both fundamental and applied aspects of catalysis are covered. Subjects such as catalysis of immobilized organometallic and biocatalytic systems are welcome. Subjects related to catalysis such as experimental techniques, adsorption, process technology, synthesis, in situ characterization, computational, theoretical modeling, imaging and others are included if there is a clear relationship to catalysis.