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通过双功能联苯-2-酰基膦配体形成2,3-二氢呋喃使得金催化的2-壬-1-醇或α-烯醇环异构化

IF 3.3 2区 化学 Q1 CHEMISTRY, ORGANIC
Journal of Organic Chemistry Pub Date : 2025-05-12 DOI:10.1021/acs.joc.5c0080110.1021/acs.joc.5c00801
Xiaoni Jia, Yuanmeng Kan, Wenguang Li, Weiguang Kong, Jian Wang, Ming Chen* and Ting Li*, 
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引用次数: 0

摘要

在这项工作中，我们报道了在温和的反应条件下，金催化丁-2-炔-1-醇的分子内环异构化，以构建2,3-二氢呋喃。双功能膦配体使金催化成为可能，该反应可耐受一系列取代基并表现出良好的效率。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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Formation of 2,3-Dihydrofurans via Bifunctional Biphenyl-2-ylphosphine Ligand Enables Gold-Catalyzed Cyclo-Isomerization of But-2-yn-1-ols or α-Allenols

In this work, we report a gold-catalyzed intramolecular cyclo-isomerization of but-2-yn-1-ols for the construction of 2,3-dihydrofurans under mild reaction conditions. The gold catalysis is enabled by a bifunctional phosphine ligand, and the reaction tolerates a range of substituents and exhibits good efficiencies.

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来源期刊
Journal of Organic Chemistry
Journal of Organic Chemistry 化学-有机化学
CiteScore
6.20
自引率
11.10%
发文量
1467
审稿时长
2 months
期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.
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