溶胶-凝胶法制备钇掺杂ZnO纳米颗粒的热释光行为

IF 3.2 4区 化学 Q2 CHEMISTRY, ANALYTICAL
Luminescence Pub Date : 2025-05-21 DOI:10.1002/bio.70199
M. Isik, T. Yildirim, N. M. Gasanly
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引用次数: 0

摘要

研制高效的热释光材料是进行精确辐射剂量测定的必要条件。本研究合成了钇掺杂ZnO纳米粒子,并对其结构和热释光特性进行了系统分析。x射线衍射证实了六方ZnO相的保存,而透射电子显微镜显示了分散良好的纳米颗粒。TL测量显示出强烈的剂量依赖性响应,发光曲线显示出与不同捕获中心相关的多个峰。反褶积分析确定了三个主要圈闭级别,活化能分别为0.77、1.12和1.29 eV,表明存在深圈闭和浅圈闭。辐射强度随辐射剂量呈线性变化,表明Y:ZnO纳米颗粒适合于剂量学应用。通过光致发光(PL)分析研究了钇掺杂对ZnO纳米粒子光学性能的影响,发现Y掺杂显著增强了缺陷相关发射。这些发现突出了Y:ZnO作为先进辐射传感技术的有前途的候选者的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Thermoluminescence Behavior of Yttrium-Doped ZnO Nanoparticles Synthesized by Sol–Gel Method

The development of efficient thermoluminescent materials is essential for precise radiation dosimetry. In this study, yttrium-doped ZnO (Y:ZnO) nanoparticles were synthesized and systematically analyzed to explore their structural and thermoluminescence (TL) properties. X-ray diffraction confirmed the preservation of the hexagonal ZnO phase, while transmission electron microscopy revealed well-dispersed nanoparticles. TL measurements exhibited a strong dose-dependent response, with glow curves showing multiple peaks associated with distinct trapping centers. Deconvolution analysis identified three primary trap levels with activation energies of 0.77, 1.12, and 1.29 eV, indicating the presence of deep and shallow traps. The TL intensity followed a linear trend with radiation dose, suggesting the suitability of Y:ZnO nanoparticles for dosimetric applications. Photoluminescence (PL) analysis was conducted to investigate the influence of yttrium doping on the optical properties of ZnO nanoparticles, and it was found that Y doping significantly enhanced defect-related emissions. These findings highlight the potential of Y:ZnO as a promising candidate for advanced radiation sensing technologies.

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来源期刊
Luminescence
Luminescence 生物-生化与分子生物学
CiteScore
5.10
自引率
13.80%
发文量
248
审稿时长
3.5 months
期刊介绍: Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry. Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.
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