微波辅助Cu(OAc)2催化苯酚与卤代芳烃的o -芳基化反应

IF 0.9 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-05-21 DOI:10.1134/S1070363224612791

V. Jadhav, I. Jamadar, R. G. Kalkhambkar, M. S. Refat, A. Mohammed Alsuhaibani

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引用次数: 0

摘要

用Cu催化剂在胍离子液体（GIL）中进行了直接、环保的苯酚与不同取代卤代芳烃o-芳基化反应。用绿色化学的方法证明了金属催化剂在GIL中生成C-O键。该方法为在温和的反应条件下合成各种联芳醚提供了有效途径。该方法的另一个优点是，可以有效地回收和重复使用多达五个循环。

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Cu(OAc)2 Catalyzed, Microwave Assisted O-Arylation of Phenols with Haloarenes Using Guanidinium Ionic Liquids as Recyclable System Under Mild Reaction Conditions

Microwaves assisted straightforward and eco-friendly O-arylation of phenols with different substituted haloarenes has been demonstrated using Cu catalyst in guanidinium ionic liquid (GIL). The generation of the C–O bond via metal catalyst in GIL is demonstrated using green chemistry approach. This method provides an effective way to synthesize various biaryl ethers under mild reaction conditions. The effective recyclability and reusability of GIL up to five cycles have been performed very successfully which is the additional advantages of this method.

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.