N. V. Chizhova, A. E. Likhonina, N. Z. Mamardashvili
{"title":"Mg（II）、Zn（II）、Cu（II）和Mn（III）八氧基（3-氟苯基）四氮卟啉的合成、光谱和光化学性质","authors":"N. V. Chizhova, A. E. Likhonina, N. Z. Mamardashvili","doi":"10.1134/S1070363225600389","DOIUrl":null,"url":null,"abstract":"<p>Mg(II)-octa-(3-fluorophenyl)tetraazaporphyrin and Zn(II)-octa-(3-fluorophenyl)tetraazaporphyrin were synthesized by boiling di-(3-fluorophenyl)maleic acid dinitrile with magnesium and zinc acetates in ethylene glycol. The corresponding Cu(II) and Mn(III)-porphyrazines were synthesized using the metal exchange reaction of the <i>meta</i>-fluoro-substituted magnesium complex with copper(II) and manganese(II) chlorides in dimethylformamide. The obtained compounds were identified by UV-Vis, <sup>1</sup>H and <sup>13</sup> C NMR spectroscopy, mass spectrometry and elemental analysis methods. The fluorescence quantum yields of the studied complexes in tetrahydrofuran were determined. The photochemical stability of the synthesized complexes was studied.</p>","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 5","pages":"1075 - 1085"},"PeriodicalIF":0.8000,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Spectral, and Photochemical Properties of Mg(II), Zn(II), Cu(II), and Mn(III) Octa-(3-fluorophenyl)tetraazaporphyrins\",\"authors\":\"N. V. Chizhova, A. E. Likhonina, N. Z. Mamardashvili\",\"doi\":\"10.1134/S1070363225600389\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Mg(II)-octa-(3-fluorophenyl)tetraazaporphyrin and Zn(II)-octa-(3-fluorophenyl)tetraazaporphyrin were synthesized by boiling di-(3-fluorophenyl)maleic acid dinitrile with magnesium and zinc acetates in ethylene glycol. The corresponding Cu(II) and Mn(III)-porphyrazines were synthesized using the metal exchange reaction of the <i>meta</i>-fluoro-substituted magnesium complex with copper(II) and manganese(II) chlorides in dimethylformamide. The obtained compounds were identified by UV-Vis, <sup>1</sup>H and <sup>13</sup> C NMR spectroscopy, mass spectrometry and elemental analysis methods. The fluorescence quantum yields of the studied complexes in tetrahydrofuran were determined. The photochemical stability of the synthesized complexes was studied.</p>\",\"PeriodicalId\":761,\"journal\":{\"name\":\"Russian Journal of General Chemistry\",\"volume\":\"95 5\",\"pages\":\"1075 - 1085\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2025-05-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of General Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070363225600389\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of General Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070363225600389","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis, Spectral, and Photochemical Properties of Mg(II), Zn(II), Cu(II), and Mn(III) Octa-(3-fluorophenyl)tetraazaporphyrins
Mg(II)-octa-(3-fluorophenyl)tetraazaporphyrin and Zn(II)-octa-(3-fluorophenyl)tetraazaporphyrin were synthesized by boiling di-(3-fluorophenyl)maleic acid dinitrile with magnesium and zinc acetates in ethylene glycol. The corresponding Cu(II) and Mn(III)-porphyrazines were synthesized using the metal exchange reaction of the meta-fluoro-substituted magnesium complex with copper(II) and manganese(II) chlorides in dimethylformamide. The obtained compounds were identified by UV-Vis, 1H and 13 C NMR spectroscopy, mass spectrometry and elemental analysis methods. The fluorescence quantum yields of the studied complexes in tetrahydrofuran were determined. The photochemical stability of the synthesized complexes was studied.
期刊介绍：
Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
