BN-embedded aromatic hydrocarbons: synthesis, functionalization and applications

Substituting CC double bonds with B–N bonds in polycyclic aromatic hydrocarbons (PAHs) has emerged as a promising approach to advance and diversify organic functional materials. This structural modification not only imparts unique electronic and optical properties, but also enhances chemical stability, thereby opening new avenues for material design and applications. However, the widespread adoption of BN-fused aromatic hydrocarbons in practical applications is still in its nascent phase. This constraint stems primarily from the challenges in precisely tailoring molecular structures to optimize photophysical and electronic properties, thereby influencing their efficacy in targeted applications. Consequently, a comprehensive evaluation of historical, current, and prospective developments in BN-fused aromatic hydrocarbons is deemed essential. This review offers an in-depth overview of recent advancements in BN-fused aromatic hydrocarbons, focusing on synthetic strategies, fundamental properties, and emerging applications. Additionally, we elucidate the pivotal role of computational chemistry in directing the design, discovery, and optimization of these materials. Our objective is to foster interdisciplinary collaboration and stimulate innovative approaches to fully harness the potential of azaborinine chemistry across various fields, including organic optoelectronics, biomedicine, and related disciplines.