用Co-MOF包覆间隔TiO2纳米管阵列光阳极对304不锈钢的腐蚀防护

IF 5.5 3区材料科学 Q1 ELECTROCHEMISTRY

Electrochimica Acta Pub Date : 2025-05-20 DOI:10.1016/j.electacta.2025.146514

Qianxilong Wang , Jiakuo Chen , Jiansheng Wang , Xiongfeng Zeng , Ruimin Wang , Yingna Zhao

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引用次数: 0

摘要

本文设计并制备了具有间隙特性的TiO2纳米管阵列。此外，通过调整金属离子与配体的比例（1:20），获得了完全包覆的Co-MOF/TiO2复合光阳极；其次，采用XPS和EPR等测试并结合理论计算验证II型异质结的构建，促进了光生电子-空穴对的分离，从而增强了复合光阳极的阴极保护效果。最后，为了推广绿色环保的防腐材料，深入研究了复合光阳极在304SS上不同应用区域（1cm2, 25cm2100 cm2）的防腐和抗点蚀效果。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Corrosion protection of large-scale 304 stainless steel via Co-MOF coated the spaced TiO2 nanotube array photoanodes

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Corrosion protection of large-scale 304 stainless steel via Co-MOF coated the spaced TiO2 nanotube array photoanodes

In this paper, TiO₂ nanotube arrays with gap characteristics were designed and fabricated. Moreover, by adjusting the ratio of metal ions to ligands (1:20), a fully coated Co-MOF/TiO₂ composite photoanode was obtained; Secondly, tests such as XPS and EPR were adopted and combined with theoretical calculations to verify the construction of Type II heterojunctions, which promoted the separation of photogenerated electron-hole pairs and thereby enhanced the cathodic protection effect of the composite photoanode. Finally, to promote green and environmentally friendly anti-corrosion materials, an in-depth study was conducted on the anti-corrosion and anti-pitting effects of composite photoanodes on 304SS with different application areas (1cm²,25cm²,100cm²).

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来源期刊

Electrochimica Acta 工程技术-电化学

CiteScore

11.30

自引率

6.10%

发文量

1634

审稿时长

41 days

期刊介绍： Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.