{"title":"通过难熔夹杂物的钛和铬同位素分析来限制球粒体材料同位素变化的来源","authors":"Yuki Masuda , Tetsuya Yokoyama , Tsuyoshi Iizuka , Yuki Hibiya","doi":"10.1016/j.epsl.2025.119447","DOIUrl":null,"url":null,"abstract":"<div><div>Nucleosynthetic isotope anomalies in meteorites indicate a non-uniform distribution of stable isotopes in the protosolar disk. Understanding the origin of the isotopic dichotomy between carbonaceous chondrites (CCs) and non-carbonaceous (NCs) meteorites, especially in Ti (ε<sup>50</sup>Ti) and Cr (ε<sup>54</sup>Cr), is essential for exploring the early evolution of the Solar System and the planetesimal formation. Calcium-aluminum-rich inclusions (CAIs), the oldest Solar System condensates rich in CCs, control the isotopic compositions of refractory elements in CCs. However, the Ti-Cr isotopic compositions of CCs cannot be solely ascribed to commonly studied coarse-grained CAIs (CGs). Fine-grained CAIs (FGs), which have avoided melting after condensation, likely preserve the isotopic signature of CAI-forming gases, making them important for understanding the isotopic compositions of CCs and the origin of the NC<img>CC isotopic dichotomy.</div><div>This study investigates the Ti-Cr isotopic compositions of ten FGs and four CGs from three CV chondrites. These CAIs exhibit ε<sup>50</sup>Ti values consistent with previous studies, while their ε<sup>54</sup>Cr values are more variable than were previously obtained. Notably, some FGs present higher ε<sup>54</sup>Cr and ε<sup>50</sup>Ti values than CGs, suggesting a distinct origin for FGs that cannot be attributed to the matrix–CG mixing. Moreover, our results indicate that the diversity in isotopic composition of CCs cannot be fully explained by differences in the abundance of refractory materials among individual CCs. The negative correlation between ε<sup>50</sup>Ti and ε<sup>54</sup>Cr values in CCs suggests that the isotopic variability arose from either metal grains with low ε<sup>54</sup>Cr values, or differences in isotopic composition among each CC matrix.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"664 ","pages":"Article 119447"},"PeriodicalIF":4.8000,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Constraining the origin of isotopic variations in chondritic materials through titanium and chromium isotopic analyses of refractory inclusions\",\"authors\":\"Yuki Masuda , Tetsuya Yokoyama , Tsuyoshi Iizuka , Yuki Hibiya\",\"doi\":\"10.1016/j.epsl.2025.119447\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Nucleosynthetic isotope anomalies in meteorites indicate a non-uniform distribution of stable isotopes in the protosolar disk. Understanding the origin of the isotopic dichotomy between carbonaceous chondrites (CCs) and non-carbonaceous (NCs) meteorites, especially in Ti (ε<sup>50</sup>Ti) and Cr (ε<sup>54</sup>Cr), is essential for exploring the early evolution of the Solar System and the planetesimal formation. Calcium-aluminum-rich inclusions (CAIs), the oldest Solar System condensates rich in CCs, control the isotopic compositions of refractory elements in CCs. However, the Ti-Cr isotopic compositions of CCs cannot be solely ascribed to commonly studied coarse-grained CAIs (CGs). Fine-grained CAIs (FGs), which have avoided melting after condensation, likely preserve the isotopic signature of CAI-forming gases, making them important for understanding the isotopic compositions of CCs and the origin of the NC<img>CC isotopic dichotomy.</div><div>This study investigates the Ti-Cr isotopic compositions of ten FGs and four CGs from three CV chondrites. These CAIs exhibit ε<sup>50</sup>Ti values consistent with previous studies, while their ε<sup>54</sup>Cr values are more variable than were previously obtained. Notably, some FGs present higher ε<sup>54</sup>Cr and ε<sup>50</sup>Ti values than CGs, suggesting a distinct origin for FGs that cannot be attributed to the matrix–CG mixing. Moreover, our results indicate that the diversity in isotopic composition of CCs cannot be fully explained by differences in the abundance of refractory materials among individual CCs. The negative correlation between ε<sup>50</sup>Ti and ε<sup>54</sup>Cr values in CCs suggests that the isotopic variability arose from either metal grains with low ε<sup>54</sup>Cr values, or differences in isotopic composition among each CC matrix.</div></div>\",\"PeriodicalId\":11481,\"journal\":{\"name\":\"Earth and Planetary Science Letters\",\"volume\":\"664 \",\"pages\":\"Article 119447\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-05-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Earth and Planetary Science Letters\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0012821X25002468\",\"RegionNum\":1,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Earth and Planetary Science Letters","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0012821X25002468","RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Constraining the origin of isotopic variations in chondritic materials through titanium and chromium isotopic analyses of refractory inclusions
Nucleosynthetic isotope anomalies in meteorites indicate a non-uniform distribution of stable isotopes in the protosolar disk. Understanding the origin of the isotopic dichotomy between carbonaceous chondrites (CCs) and non-carbonaceous (NCs) meteorites, especially in Ti (ε50Ti) and Cr (ε54Cr), is essential for exploring the early evolution of the Solar System and the planetesimal formation. Calcium-aluminum-rich inclusions (CAIs), the oldest Solar System condensates rich in CCs, control the isotopic compositions of refractory elements in CCs. However, the Ti-Cr isotopic compositions of CCs cannot be solely ascribed to commonly studied coarse-grained CAIs (CGs). Fine-grained CAIs (FGs), which have avoided melting after condensation, likely preserve the isotopic signature of CAI-forming gases, making them important for understanding the isotopic compositions of CCs and the origin of the NCCC isotopic dichotomy.
This study investigates the Ti-Cr isotopic compositions of ten FGs and four CGs from three CV chondrites. These CAIs exhibit ε50Ti values consistent with previous studies, while their ε54Cr values are more variable than were previously obtained. Notably, some FGs present higher ε54Cr and ε50Ti values than CGs, suggesting a distinct origin for FGs that cannot be attributed to the matrix–CG mixing. Moreover, our results indicate that the diversity in isotopic composition of CCs cannot be fully explained by differences in the abundance of refractory materials among individual CCs. The negative correlation between ε50Ti and ε54Cr values in CCs suggests that the isotopic variability arose from either metal grains with low ε54Cr values, or differences in isotopic composition among each CC matrix.
期刊介绍:
Earth and Planetary Science Letters (EPSL) is a leading journal for researchers across the entire Earth and planetary sciences community. It publishes concise, exciting, high-impact articles ("Letters") of broad interest. Its focus is on physical and chemical processes, the evolution and general properties of the Earth and planets - from their deep interiors to their atmospheres. EPSL also includes a Frontiers section, featuring invited high-profile synthesis articles by leading experts on timely topics to bring cutting-edge research to the wider community.