通过难熔夹杂物的钛和铬同位素分析来限制球粒体材料同位素变化的来源

IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Yuki Masuda , Tetsuya Yokoyama , Tsuyoshi Iizuka , Yuki Hibiya
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引用次数: 0

摘要

陨石中的核合成同位素异常表明原太阳盘中稳定同位素的分布不均匀。了解碳质球粒陨石(CCs)和非碳质球粒陨石(nc),特别是Ti (ε50Ti)和Cr (ε54Cr)同位素二分法的起源,对于探索太阳系早期演化和星子形成具有重要意义。富钙铝包裹体(CAIs)是太阳系中最古老的富碳凝析物,控制着碳中难熔元素的同位素组成。然而,cc的Ti-Cr同位素组成不能仅仅归因于通常研究的粗粒CAIs (CGs)。细粒CAIs (FGs)在凝结后避免融化,可能保留了形成CAIs的气体的同位素特征,这对于理解CCs的同位素组成和NCCC同位素二分法的起源很重要。本文研究了3个CV球粒中10个fg和4个cg的Ti-Cr同位素组成。这些cai的ε50Ti值与前人的研究结果一致,而ε54Cr值则比前人的研究结果变化更大。值得注意的是,一些fg的ε54Cr和ε50Ti值高于cg,这表明fg的起源不同,不能归因于基质- cg混合。此外,我们的研究结果表明,CCs同位素组成的多样性不能完全用单个CCs之间耐火材料丰度的差异来解释。CC中ε50Ti值与ε54Cr值呈负相关,说明各CC基体的同位素组成差异可能是由低ε54Cr值的金属颗粒引起的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Constraining the origin of isotopic variations in chondritic materials through titanium and chromium isotopic analyses of refractory inclusions
Nucleosynthetic isotope anomalies in meteorites indicate a non-uniform distribution of stable isotopes in the protosolar disk. Understanding the origin of the isotopic dichotomy between carbonaceous chondrites (CCs) and non-carbonaceous (NCs) meteorites, especially in Ti (ε50Ti) and Cr (ε54Cr), is essential for exploring the early evolution of the Solar System and the planetesimal formation. Calcium-aluminum-rich inclusions (CAIs), the oldest Solar System condensates rich in CCs, control the isotopic compositions of refractory elements in CCs. However, the Ti-Cr isotopic compositions of CCs cannot be solely ascribed to commonly studied coarse-grained CAIs (CGs). Fine-grained CAIs (FGs), which have avoided melting after condensation, likely preserve the isotopic signature of CAI-forming gases, making them important for understanding the isotopic compositions of CCs and the origin of the NCCC isotopic dichotomy.
This study investigates the Ti-Cr isotopic compositions of ten FGs and four CGs from three CV chondrites. These CAIs exhibit ε50Ti values consistent with previous studies, while their ε54Cr values are more variable than were previously obtained. Notably, some FGs present higher ε54Cr and ε50Ti values than CGs, suggesting a distinct origin for FGs that cannot be attributed to the matrix–CG mixing. Moreover, our results indicate that the diversity in isotopic composition of CCs cannot be fully explained by differences in the abundance of refractory materials among individual CCs. The negative correlation between ε50Ti and ε54Cr values in CCs suggests that the isotopic variability arose from either metal grains with low ε54Cr values, or differences in isotopic composition among each CC matrix.
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来源期刊
Earth and Planetary Science Letters
Earth and Planetary Science Letters 地学-地球化学与地球物理
CiteScore
10.30
自引率
5.70%
发文量
475
审稿时长
2.8 months
期刊介绍: Earth and Planetary Science Letters (EPSL) is a leading journal for researchers across the entire Earth and planetary sciences community. It publishes concise, exciting, high-impact articles ("Letters") of broad interest. Its focus is on physical and chemical processes, the evolution and general properties of the Earth and planets - from their deep interiors to their atmospheres. EPSL also includes a Frontiers section, featuring invited high-profile synthesis articles by leading experts on timely topics to bring cutting-edge research to the wider community.
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