{"title":"远紫外二次谐波金属有机气相外延生长AlGaN/AlN应变层超晶格","authors":"Shahzeb Malik*, Masaaki Ito, Hiroto Honda, Ryosuke Noro, Kanako Shojiki, Hideto Miyake, Masahiro Uemukai, Tomoyuki Tanikawa* and Ryuji Katayama, ","doi":"10.1021/acs.cgd.4c0132510.1021/acs.cgd.4c01325","DOIUrl":null,"url":null,"abstract":"<p >Ultrathin AlN (<100 nm) layers fabricated via sputtering and subsequent face-to-face annealing (SP-FFA) over sapphire substrates can be applied as templates for the growth of AlGaN/AlN-based second harmonic generation (SHG) devices due to the high crystalline quality and smooth surface. This paper provides a concise overview of the crystalline characteristics of SP-FFA and metalorganic vapor phase epitaxy. An atomic force microscopy obtained a root-mean-square (RMS) roughness of 0.13 nm after the ultrathin growth of SP-FFA AlN. Subsequently, the impact of the SP-FFA AlN template on the regrowth of AlN and AlGaN by metalorganic vapor phase epitaxy has been examined. The phenomenon of the strong composition-pulling effect for the growth of AlGaN on the SP-FFA AlN template has been discussed. Finally, the paper discusses the successful growth of Al<sub>0.88</sub>Ga<sub>0.12</sub>N/AlN strained-layer superlattices, while ensuring a smooth surface morphology with an RMS roughness value of 0.15 nm, which effectively reduces the scattering loss in a waveguide. The growth of the strained-layer superlattice augments the nonlinear coupling coefficient kappa by utilizing the piezoelectric field in the transverse quasi-phase matching SHG device.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":"25 10","pages":"3266–3273 3266–3273"},"PeriodicalIF":3.2000,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Epitaxial Growth of AlGaN/AlN Strained-Layer Superlattices by Metalorganic Vapor Phase Epitaxy for Far-UV Second Harmonic Generation\",\"authors\":\"Shahzeb Malik*, Masaaki Ito, Hiroto Honda, Ryosuke Noro, Kanako Shojiki, Hideto Miyake, Masahiro Uemukai, Tomoyuki Tanikawa* and Ryuji Katayama, \",\"doi\":\"10.1021/acs.cgd.4c0132510.1021/acs.cgd.4c01325\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Ultrathin AlN (<100 nm) layers fabricated via sputtering and subsequent face-to-face annealing (SP-FFA) over sapphire substrates can be applied as templates for the growth of AlGaN/AlN-based second harmonic generation (SHG) devices due to the high crystalline quality and smooth surface. This paper provides a concise overview of the crystalline characteristics of SP-FFA and metalorganic vapor phase epitaxy. An atomic force microscopy obtained a root-mean-square (RMS) roughness of 0.13 nm after the ultrathin growth of SP-FFA AlN. Subsequently, the impact of the SP-FFA AlN template on the regrowth of AlN and AlGaN by metalorganic vapor phase epitaxy has been examined. The phenomenon of the strong composition-pulling effect for the growth of AlGaN on the SP-FFA AlN template has been discussed. Finally, the paper discusses the successful growth of Al<sub>0.88</sub>Ga<sub>0.12</sub>N/AlN strained-layer superlattices, while ensuring a smooth surface morphology with an RMS roughness value of 0.15 nm, which effectively reduces the scattering loss in a waveguide. The growth of the strained-layer superlattice augments the nonlinear coupling coefficient kappa by utilizing the piezoelectric field in the transverse quasi-phase matching SHG device.</p>\",\"PeriodicalId\":34,\"journal\":{\"name\":\"Crystal Growth & Design\",\"volume\":\"25 10\",\"pages\":\"3266–3273 3266–3273\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-05-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Growth & Design\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01325\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Growth & Design","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.4c01325","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Epitaxial Growth of AlGaN/AlN Strained-Layer Superlattices by Metalorganic Vapor Phase Epitaxy for Far-UV Second Harmonic Generation
Ultrathin AlN (<100 nm) layers fabricated via sputtering and subsequent face-to-face annealing (SP-FFA) over sapphire substrates can be applied as templates for the growth of AlGaN/AlN-based second harmonic generation (SHG) devices due to the high crystalline quality and smooth surface. This paper provides a concise overview of the crystalline characteristics of SP-FFA and metalorganic vapor phase epitaxy. An atomic force microscopy obtained a root-mean-square (RMS) roughness of 0.13 nm after the ultrathin growth of SP-FFA AlN. Subsequently, the impact of the SP-FFA AlN template on the regrowth of AlN and AlGaN by metalorganic vapor phase epitaxy has been examined. The phenomenon of the strong composition-pulling effect for the growth of AlGaN on the SP-FFA AlN template has been discussed. Finally, the paper discusses the successful growth of Al0.88Ga0.12N/AlN strained-layer superlattices, while ensuring a smooth surface morphology with an RMS roughness value of 0.15 nm, which effectively reduces the scattering loss in a waveguide. The growth of the strained-layer superlattice augments the nonlinear coupling coefficient kappa by utilizing the piezoelectric field in the transverse quasi-phase matching SHG device.
期刊介绍:
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.