铜催化乙烯烯与n -氟苯磺酰亚胺和三甲基硅唑衍生物的三组分自由基氨基唑化反应

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-05-20 DOI:10.1039/d5cc01080b

Qingbing Yuan, Caiqiong Wu, Yonghu Bao, ZeMing Huang, Hua Wang, Yun Wei, Shaowu Wang

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引用次数: 0

摘要

研究了乙烯烯与n -氟苯磺酰亚胺（NFSI）和三甲基硅唑衍生物的铜催化三组分自由基氨基唑化反应。该方法提供了一种高效、简单的方法来生成各种β-磺基氨基唑，收率很高。该方案具有独特的化学和区域选择性，在温和条件下具有优异的官能团耐受性。

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Copper-catalyzed three-component radical aminoazolation of vinylarenes with N-fluorobenzenesulfonimide and trimethylsilylazole derivatives

A copper-catalyzed three-component radical aminoazolation of vinylarenes with N-fluorobenzenesulfonimide (NFSI) and trimethylsilylazole derivatives has been developed. This methodology provides an efficient and straightforward approach to generate various β-sulfoamino azoles in good to excellent yields. The protocol features exclusive chemo- and regioselectivity, excellent functional group tolerance under mild conditions.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.