Xueying Lyu, Yuan Wang, Jiamin Zhang, Sen Yang, Yuting Zhang, Youlu Jiang, Jingdong Liu
{"title":"原油成因与油源相关性聚类分析——以沧东坳陷为例","authors":"Xueying Lyu, Yuan Wang, Jiamin Zhang, Sen Yang, Yuting Zhang, Youlu Jiang, Jingdong Liu","doi":"10.1021/acsomega.5c01400","DOIUrl":null,"url":null,"abstract":"<p><p>In a petroliferous basin with multiple sets of source rocks, determining the origins of hydrocarbons and their mixed ratios is a crucial aspect of hydrocarbon accumulation mechanisms. Focusing on the Mesozoic-Paleozoic reservoirs within the Cangdong Depression, this study began with source-source comparisons to identify key distinguishing parameters. This was followed by oil-oil correlations using the cluster analysis method. And then, oil source correlations were performed to determine the origins of each type of crude oil. On this basis, a quantitative method for predicting the proportion of mixed crude oil sources was proposed. The results show that the Ek<sub>2</sub> and C-P source rocks are both rich in organic matter. However, the Ek<sub>2</sub> source rocks are predominantly sapropelic and humic-sapropelic and favorable for oil generation. However, the C-P source rocks are primarily humic-sapropelic and more conducive for gas generation. Using cluster analysis, the Meso-Paleozoic crude oils in the Cangdong Depression are classified into two main types. Type I crude oil is primarily derived from C-P coaly mesure source rocks, while Type II crude oil is mainly sourced from the Ek<sub>2</sub> source rocks. Additionally, the oil source index (OSI) was proposed, involving physical property, carbon isotope, Ts/Tm, C<sub>30</sub>-/C<sub>29</sub>-Hopane, C<sub>27</sub>-/C<sub>29</sub>-regular sterane, and tricyclic terpene/C<sub>30</sub>-Hopane. An OSI greater than 1.20 indicates a source of Ek<sub>2</sub>, while an OSI less than or equal to 0.40 suggests humic oils derived from C-P source rocks. When the OSI falls between 0.40 and 1.20, crude oil is classified as a mixed-source oil. The proportion of mixed sources can be determined by the OSI value's proximity to the two end-point values. This study provides a valuable reference for analyzing the origin of crude oil in similar basins.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"10 18","pages":"19061-19072"},"PeriodicalIF":4.3000,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12079231/pdf/","citationCount":"0","resultStr":"{\"title\":\"Cluster Analysis of Crude Oil Genesis and Oil Source Correlation: A Case Study from the Cangdong Depression, East China.\",\"authors\":\"Xueying Lyu, Yuan Wang, Jiamin Zhang, Sen Yang, Yuting Zhang, Youlu Jiang, Jingdong Liu\",\"doi\":\"10.1021/acsomega.5c01400\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In a petroliferous basin with multiple sets of source rocks, determining the origins of hydrocarbons and their mixed ratios is a crucial aspect of hydrocarbon accumulation mechanisms. Focusing on the Mesozoic-Paleozoic reservoirs within the Cangdong Depression, this study began with source-source comparisons to identify key distinguishing parameters. This was followed by oil-oil correlations using the cluster analysis method. And then, oil source correlations were performed to determine the origins of each type of crude oil. On this basis, a quantitative method for predicting the proportion of mixed crude oil sources was proposed. The results show that the Ek<sub>2</sub> and C-P source rocks are both rich in organic matter. However, the Ek<sub>2</sub> source rocks are predominantly sapropelic and humic-sapropelic and favorable for oil generation. However, the C-P source rocks are primarily humic-sapropelic and more conducive for gas generation. Using cluster analysis, the Meso-Paleozoic crude oils in the Cangdong Depression are classified into two main types. Type I crude oil is primarily derived from C-P coaly mesure source rocks, while Type II crude oil is mainly sourced from the Ek<sub>2</sub> source rocks. Additionally, the oil source index (OSI) was proposed, involving physical property, carbon isotope, Ts/Tm, C<sub>30</sub>-/C<sub>29</sub>-Hopane, C<sub>27</sub>-/C<sub>29</sub>-regular sterane, and tricyclic terpene/C<sub>30</sub>-Hopane. An OSI greater than 1.20 indicates a source of Ek<sub>2</sub>, while an OSI less than or equal to 0.40 suggests humic oils derived from C-P source rocks. When the OSI falls between 0.40 and 1.20, crude oil is classified as a mixed-source oil. The proportion of mixed sources can be determined by the OSI value's proximity to the two end-point values. 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Cluster Analysis of Crude Oil Genesis and Oil Source Correlation: A Case Study from the Cangdong Depression, East China.
In a petroliferous basin with multiple sets of source rocks, determining the origins of hydrocarbons and their mixed ratios is a crucial aspect of hydrocarbon accumulation mechanisms. Focusing on the Mesozoic-Paleozoic reservoirs within the Cangdong Depression, this study began with source-source comparisons to identify key distinguishing parameters. This was followed by oil-oil correlations using the cluster analysis method. And then, oil source correlations were performed to determine the origins of each type of crude oil. On this basis, a quantitative method for predicting the proportion of mixed crude oil sources was proposed. The results show that the Ek2 and C-P source rocks are both rich in organic matter. However, the Ek2 source rocks are predominantly sapropelic and humic-sapropelic and favorable for oil generation. However, the C-P source rocks are primarily humic-sapropelic and more conducive for gas generation. Using cluster analysis, the Meso-Paleozoic crude oils in the Cangdong Depression are classified into two main types. Type I crude oil is primarily derived from C-P coaly mesure source rocks, while Type II crude oil is mainly sourced from the Ek2 source rocks. Additionally, the oil source index (OSI) was proposed, involving physical property, carbon isotope, Ts/Tm, C30-/C29-Hopane, C27-/C29-regular sterane, and tricyclic terpene/C30-Hopane. An OSI greater than 1.20 indicates a source of Ek2, while an OSI less than or equal to 0.40 suggests humic oils derived from C-P source rocks. When the OSI falls between 0.40 and 1.20, crude oil is classified as a mixed-source oil. The proportion of mixed sources can be determined by the OSI value's proximity to the two end-point values. This study provides a valuable reference for analyzing the origin of crude oil in similar basins.
ACS OmegaChemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍:
ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.