{"title":"FAU沸石种子辅助沸石间转化合成mww型沸石","authors":"Mengxuan Zhu, Yifan Liu, Jiaxin Ma, Longyang Wang, Rui Wang, Heng Jiang, Changzi Jin","doi":"10.1007/s10971-025-06769-7","DOIUrl":null,"url":null,"abstract":"<div><p>Developing the novel green routes for synthesis of important aluminosilicate zeolites is of significant for theoretical research and practical application. In this work, MCM-22 zeolite with MWW-topology was synthesized through seed-assisted interzeolite transformation from FAU zeolite without using additional organic template. The key influence factor to the synthesis process was investigated and the zeolite products were characterized by a series of modern techniques. It has been shown that not only the presence of MCM-22 seed, but also the appropriate SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> and Na<sub>2</sub>O/SiO<sub>2</sub> molar ratio of starting synthesis gel with were crucial to synthesize pure MWW zeolite. The hexamethyleneimine template occluded in seed also played a key role in successful interzeolite transformation, but did not participate structure-directing of MWW product. Although the zeolite synthesized by interzeolite transformation showed lower surface area and pore volume compared with MCM-22 zeolite prepared by conventional route, the Pt modified sample exhibited promising catalytic performance in hydroisomerization of <i>n</i>-heptane.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":"114 3","pages":"1029 - 1039"},"PeriodicalIF":3.2000,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of MWW-type zeolite through seed-assisted interzeolite transformation from FAU zeolite\",\"authors\":\"Mengxuan Zhu, Yifan Liu, Jiaxin Ma, Longyang Wang, Rui Wang, Heng Jiang, Changzi Jin\",\"doi\":\"10.1007/s10971-025-06769-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Developing the novel green routes for synthesis of important aluminosilicate zeolites is of significant for theoretical research and practical application. In this work, MCM-22 zeolite with MWW-topology was synthesized through seed-assisted interzeolite transformation from FAU zeolite without using additional organic template. The key influence factor to the synthesis process was investigated and the zeolite products were characterized by a series of modern techniques. It has been shown that not only the presence of MCM-22 seed, but also the appropriate SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> and Na<sub>2</sub>O/SiO<sub>2</sub> molar ratio of starting synthesis gel with were crucial to synthesize pure MWW zeolite. The hexamethyleneimine template occluded in seed also played a key role in successful interzeolite transformation, but did not participate structure-directing of MWW product. Although the zeolite synthesized by interzeolite transformation showed lower surface area and pore volume compared with MCM-22 zeolite prepared by conventional route, the Pt modified sample exhibited promising catalytic performance in hydroisomerization of <i>n</i>-heptane.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":664,\"journal\":{\"name\":\"Journal of Sol-Gel Science and Technology\",\"volume\":\"114 3\",\"pages\":\"1029 - 1039\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2025-04-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Sol-Gel Science and Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10971-025-06769-7\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Sol-Gel Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10971-025-06769-7","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Synthesis of MWW-type zeolite through seed-assisted interzeolite transformation from FAU zeolite
Developing the novel green routes for synthesis of important aluminosilicate zeolites is of significant for theoretical research and practical application. In this work, MCM-22 zeolite with MWW-topology was synthesized through seed-assisted interzeolite transformation from FAU zeolite without using additional organic template. The key influence factor to the synthesis process was investigated and the zeolite products were characterized by a series of modern techniques. It has been shown that not only the presence of MCM-22 seed, but also the appropriate SiO2/Al2O3 and Na2O/SiO2 molar ratio of starting synthesis gel with were crucial to synthesize pure MWW zeolite. The hexamethyleneimine template occluded in seed also played a key role in successful interzeolite transformation, but did not participate structure-directing of MWW product. Although the zeolite synthesized by interzeolite transformation showed lower surface area and pore volume compared with MCM-22 zeolite prepared by conventional route, the Pt modified sample exhibited promising catalytic performance in hydroisomerization of n-heptane.
期刊介绍：
The primary objective of the Journal of Sol-Gel Science and Technology (JSST), the official journal of the International Sol-Gel Society, is to provide an international forum for the dissemination of scientific, technological, and general knowledge about materials processed by chemical nanotechnologies known as the "sol-gel" process. The materials of interest include gels, gel-derived glasses, ceramics in form of nano- and micro-powders, bulk, fibres, thin films and coatings as well as more recent materials such as hybrid organic-inorganic materials and composites. Such materials exhibit a wide range of optical, electronic, magnetic, chemical, environmental, and biomedical properties and functionalities. Methods for producing sol-gel-derived materials and the industrial uses of these materials are also of great interest.
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