Hildegard R. Kasambala, Mwemezi J. Rwiza, Nelson Mpumi, Mwema Felix Mwema, Karoli K. Njau
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The effect of other factors on adsorbent efficiency and its characteristics were subsequently analyzed by biochar calcinated at 700 °C. Results indicate that as the concentration of adsorbent increases, the adsorption efficiency increases while the adsorption capacity decreases. The Langmuir model fits better in BPB, while the Freundlich model fits better in MPB. The maximum adsorption capacities of the Langmuir model were 43.42 and 37.80 mg of progesterone per g of BPB and MPB, respectively. The scanning electron microscopy image (SEM) showed that biochar from 700 °C presents higher porosities than biochar. The Brunauer–Emmett–Teller (BET) showed that both biochars had high surface area and equal pore volume. 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引用次数: 0
摘要
本研究在分离系统中研究了从香蕉中提取的生物炭和从水中破坏内分泌干扰化合物(EDCs)的有效性。该研究旨在提供一种利用农业废弃物净化水的环保解决方案。香蕉和芒果皮在300、550和700°C的温度下干燥、研磨和煅烧。采用间歇式吸附实验检测生物炭对黄体酮的去除效果,并采用高效液相色谱法对剩余黄体酮进行分析。结果表明,香蕉皮生物炭(BPB)和芒果皮生物炭(MPB)在700℃热解时的吸附量最高,分别为92.8%和87.9%。随后,通过700℃煅烧生物炭,分析了其他因素对吸附剂效率及其特性的影响。结果表明:随着吸附剂浓度的增加,吸附效率增加,吸附容量减小;Langmuir模型更适合于BPB, Freundlich模型更适合于MPB。Langmuir模型的最大吸附量分别为43.42 mg / g BPB和37.80 mg / g MPB。扫描电镜(SEM)显示,700℃时的生物炭孔隙率高于生物炭。brunauer - emmet - teller (BET)试验表明,两种生物炭均具有较高的比表面积和相同的孔隙体积。因此,研究表明,BPB和MPB是开发可持续水处理技术去除水中EDCs的最佳生态友好型农业废弃物。
Biochars derived from banana and mango peels in isolated systems revealed high removal efficiency of endocrine-disrupting compounds from water
This study investigated the effectiveness of biochar derived from banana and disrupting endocrine-disrupting compounds (EDCs) from water in isolated systems. The study aimed to provide an eco-friendly solution for water purification using agricultural waste products. Banana and mango peels were dried, ground, and calcinated at 300, 550, and 700 °C temperatures. The biochar was tested through a batch adsorption experiment for the removal of progesterone, and the remaining progesterone was analyzed using high-performance liquid chromatography (HPLC). Results indicated that the banana peel biochar (BPB) and mango peel biochar (MPB) achieved the highest adsorption capacities of 92.8 and 87.9%, respectively, when subjected to pyrolysis at 700 °C. The effect of other factors on adsorbent efficiency and its characteristics were subsequently analyzed by biochar calcinated at 700 °C. Results indicate that as the concentration of adsorbent increases, the adsorption efficiency increases while the adsorption capacity decreases. The Langmuir model fits better in BPB, while the Freundlich model fits better in MPB. The maximum adsorption capacities of the Langmuir model were 43.42 and 37.80 mg of progesterone per g of BPB and MPB, respectively. The scanning electron microscopy image (SEM) showed that biochar from 700 °C presents higher porosities than biochar. The Brunauer–Emmett–Teller (BET) showed that both biochars had high surface area and equal pore volume. Therefore, the study suggests that BPB and MPB are the best eco-friendly agricultural waste materials for development of sustainable water treatment technologies for removal of EDCs from water.
期刊介绍:
Biomass Conversion and Biorefinery presents articles and information on research, development and applications in thermo-chemical conversion; physico-chemical conversion and bio-chemical conversion, including all necessary steps for the provision and preparation of the biomass as well as all possible downstream processing steps for the environmentally sound and economically viable provision of energy and chemical products.