{"title":"电化学合成聚苯胺- csa /金属氧化物纳米复合材料的光电特性和结构特性比较分析","authors":"Tariq AlZoubi , Mahmoud Al-Gharram , Ghaseb Makhadmeh , Osamah Abu Noqta","doi":"10.1016/j.physb.2025.417380","DOIUrl":null,"url":null,"abstract":"<div><div>The strategic integration of conductive polymers with transition metal oxide nanoparticles (NPs) offers a promising route to engineer multifunctional nanocomposite systems with tailored optoelectronic properties. In this work, we report the electrochemical synthesis and detailed characterization of PANI-CSA-based hybrid nanocomposites embedded with 12 wt% of CoFe<sub>2</sub>O<sub>4</sub>, Co<sub>3</sub>O<sub>4</sub>, and Fe<sub>2</sub>O<sub>3</sub> nanoparticles. Thin films were deposited via in situ electrodeposition onto ITO-glass substrates, enabling precise control over composition and morphology. Comprehensive optical analysis via UV–Vis spectroscopy revealed NP-induced modulation of key optical parameters, including enhanced absorption, modified refractive indices, and tunable optical bandgaps. Tauc plot analysis indicated systematic bandgap shifts ranging from 3.48 to 3.61 eV, while Urbach energy trends reflected variations in structural disorder. XRD confirmed increased crystalline and the formation of larger crystallites upon nanoparticle incorporation, consistent with interfacial ordering effects. FTIR spectra substantiated strong molecular interactions between PANI chains and metal oxide surfaces, while SEM micrographs exhibited dense fibrous morphologies supporting effective charge transport pathways. Electrical conductivity measurements, performed via a four-point probe, demonstrated high conductivity (77.3–79.9 S cm<sup>−1</sup>), with the Co<sub>3</sub>O<sub>4</sub>-based system exhibiting superior performance, attributable to enhanced crystallinity and potential p-type doping effects. Collectively, these results highlight the efficacy of metal oxide NPs as secondary dopants in modulating the optoelectronic response of PANI-CSA, positioning these hybrid films as viable candidates for advanced optoelectronic applications, including optical sensors and flexible electronic devices.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":"713 ","pages":"Article 417380"},"PeriodicalIF":2.8000,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparative analysis of optoelectronic and structural characteristics in electrochemically synthesized hybrid-nanocomposites based on PANI-CSA/metal oxide nanoparticles\",\"authors\":\"Tariq AlZoubi , Mahmoud Al-Gharram , Ghaseb Makhadmeh , Osamah Abu Noqta\",\"doi\":\"10.1016/j.physb.2025.417380\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The strategic integration of conductive polymers with transition metal oxide nanoparticles (NPs) offers a promising route to engineer multifunctional nanocomposite systems with tailored optoelectronic properties. In this work, we report the electrochemical synthesis and detailed characterization of PANI-CSA-based hybrid nanocomposites embedded with 12 wt% of CoFe<sub>2</sub>O<sub>4</sub>, Co<sub>3</sub>O<sub>4</sub>, and Fe<sub>2</sub>O<sub>3</sub> nanoparticles. Thin films were deposited via in situ electrodeposition onto ITO-glass substrates, enabling precise control over composition and morphology. Comprehensive optical analysis via UV–Vis spectroscopy revealed NP-induced modulation of key optical parameters, including enhanced absorption, modified refractive indices, and tunable optical bandgaps. Tauc plot analysis indicated systematic bandgap shifts ranging from 3.48 to 3.61 eV, while Urbach energy trends reflected variations in structural disorder. XRD confirmed increased crystalline and the formation of larger crystallites upon nanoparticle incorporation, consistent with interfacial ordering effects. FTIR spectra substantiated strong molecular interactions between PANI chains and metal oxide surfaces, while SEM micrographs exhibited dense fibrous morphologies supporting effective charge transport pathways. Electrical conductivity measurements, performed via a four-point probe, demonstrated high conductivity (77.3–79.9 S cm<sup>−1</sup>), with the Co<sub>3</sub>O<sub>4</sub>-based system exhibiting superior performance, attributable to enhanced crystallinity and potential p-type doping effects. Collectively, these results highlight the efficacy of metal oxide NPs as secondary dopants in modulating the optoelectronic response of PANI-CSA, positioning these hybrid films as viable candidates for advanced optoelectronic applications, including optical sensors and flexible electronic devices.</div></div>\",\"PeriodicalId\":20116,\"journal\":{\"name\":\"Physica B-condensed Matter\",\"volume\":\"713 \",\"pages\":\"Article 417380\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physica B-condensed Matter\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0921452625004971\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica B-condensed Matter","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921452625004971","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
引用次数: 0
摘要
导电聚合物与过渡金属氧化物纳米颗粒(NPs)的战略性集成为设计具有定制光电性能的多功能纳米复合材料系统提供了一条有前途的途径。在这项工作中,我们报告了电化学合成和详细表征的聚苯胺- csa基杂化纳米复合材料嵌入12 wt%的CoFe2O4, Co3O4和Fe2O3纳米颗粒。薄膜通过原位电沉积沉积到ito玻璃基板上,可以精确控制成分和形态。通过紫外可见光谱综合光学分析揭示了np诱导的关键光学参数调制,包括增强的吸收、改变的折射率和可调谐的光学带隙。Tauc图分析表明,带隙变化范围在3.48 ~ 3.61 eV之间,而Urbach能量趋势反映了结构无序性的变化。XRD证实纳米颗粒掺入后晶体增大,形成更大的晶体,符合界面有序效应。FTIR光谱证实了PANI链和金属氧化物表面之间强烈的分子相互作用,而SEM显微照片显示密集的纤维形态支持有效的电荷传输途径。通过四点探针进行的电导率测量表明,co3o4基体系具有高电导率(77.3-79.9 S cm−1),由于结晶度增强和潜在的p型掺杂效应,该体系表现出优异的性能。总的来说,这些结果突出了金属氧化物NPs作为二次掺杂剂在调制PANI-CSA的光电响应方面的功效,使这些混合薄膜成为先进光电应用的可行候选者,包括光学传感器和柔性电子器件。
Comparative analysis of optoelectronic and structural characteristics in electrochemically synthesized hybrid-nanocomposites based on PANI-CSA/metal oxide nanoparticles
The strategic integration of conductive polymers with transition metal oxide nanoparticles (NPs) offers a promising route to engineer multifunctional nanocomposite systems with tailored optoelectronic properties. In this work, we report the electrochemical synthesis and detailed characterization of PANI-CSA-based hybrid nanocomposites embedded with 12 wt% of CoFe2O4, Co3O4, and Fe2O3 nanoparticles. Thin films were deposited via in situ electrodeposition onto ITO-glass substrates, enabling precise control over composition and morphology. Comprehensive optical analysis via UV–Vis spectroscopy revealed NP-induced modulation of key optical parameters, including enhanced absorption, modified refractive indices, and tunable optical bandgaps. Tauc plot analysis indicated systematic bandgap shifts ranging from 3.48 to 3.61 eV, while Urbach energy trends reflected variations in structural disorder. XRD confirmed increased crystalline and the formation of larger crystallites upon nanoparticle incorporation, consistent with interfacial ordering effects. FTIR spectra substantiated strong molecular interactions between PANI chains and metal oxide surfaces, while SEM micrographs exhibited dense fibrous morphologies supporting effective charge transport pathways. Electrical conductivity measurements, performed via a four-point probe, demonstrated high conductivity (77.3–79.9 S cm−1), with the Co3O4-based system exhibiting superior performance, attributable to enhanced crystallinity and potential p-type doping effects. Collectively, these results highlight the efficacy of metal oxide NPs as secondary dopants in modulating the optoelectronic response of PANI-CSA, positioning these hybrid films as viable candidates for advanced optoelectronic applications, including optical sensors and flexible electronic devices.
期刊介绍:
Physica B: Condensed Matter comprises all condensed matter and material physics that involve theoretical, computational and experimental work.
Papers should contain further developments and a proper discussion on the physics of experimental or theoretical results in one of the following areas:
-Magnetism
-Materials physics
-Nanostructures and nanomaterials
-Optics and optical materials
-Quantum materials
-Semiconductors
-Strongly correlated systems
-Superconductivity
-Surfaces and interfaces