Dongyang Chen , Zihao Wang , Yufei Liu , Shuai Gu , Chenxiang Ai , Chunyue Pan , Guipeng Yu
{"title":"分层结构的纳米多孔有机聚合物作为监测痕量重金属离子的快速电化学平台","authors":"Dongyang Chen , Zihao Wang , Yufei Liu , Shuai Gu , Chenxiang Ai , Chunyue Pan , Guipeng Yu","doi":"10.1016/j.micromeso.2025.113685","DOIUrl":null,"url":null,"abstract":"<div><div>Rapid electrochemical monitoring and detection of toxic heavy metal ions using chemically modified carbon paste electrodes (CPEs) is of great importance, but the development of chemically stable and porous CPE substrates with unique sensing properties remains challenging. Here, we synthesized nine low-cost nanoporous organic polymer (NOP) matrices under mild CPE conditions and developed highly sensitive graphite powder (GP)@NOP composite electrodes for sensing of trace heavy metal ions. These NOP substrates have great potential for electrochemical sensing due to their large surface area, layered porosity and excellent stability. The electrochemical properties, dominated by the pore structures of the NOPs, are simply turned by regulating the nature of the building blocks and crosslinkers. The micropores facilitate highly sensitive and selective detection and the mesopores benefit mass transfer. Using GP@NOP complex electrodes, the concentrations of the analyte show linear relationship with the oxidation current peak values over a concentration range of 0.0010–0.012 μg L<sup>−1</sup> with high correlation coefficients up to 0.996. Super-high sensitivity with a low detection limit (0.0003 μg L<sup>−1</sup>) and excellent reproducibility (relative standard deviation ≤ 7.4 %) is demonstrated, superior to the pristine GP electrode and most known electrodes. This study expands a novel application for NOPs and an alternative straightforward approach for the rapid and reliable detection of heavy metal ions.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"395 ","pages":"Article 113685"},"PeriodicalIF":4.8000,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hierarchically structured nanoporous organic polymers as a rapid electrochemical platform for monitoring trace heavy metal ions\",\"authors\":\"Dongyang Chen , Zihao Wang , Yufei Liu , Shuai Gu , Chenxiang Ai , Chunyue Pan , Guipeng Yu\",\"doi\":\"10.1016/j.micromeso.2025.113685\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Rapid electrochemical monitoring and detection of toxic heavy metal ions using chemically modified carbon paste electrodes (CPEs) is of great importance, but the development of chemically stable and porous CPE substrates with unique sensing properties remains challenging. Here, we synthesized nine low-cost nanoporous organic polymer (NOP) matrices under mild CPE conditions and developed highly sensitive graphite powder (GP)@NOP composite electrodes for sensing of trace heavy metal ions. These NOP substrates have great potential for electrochemical sensing due to their large surface area, layered porosity and excellent stability. The electrochemical properties, dominated by the pore structures of the NOPs, are simply turned by regulating the nature of the building blocks and crosslinkers. The micropores facilitate highly sensitive and selective detection and the mesopores benefit mass transfer. Using GP@NOP complex electrodes, the concentrations of the analyte show linear relationship with the oxidation current peak values over a concentration range of 0.0010–0.012 μg L<sup>−1</sup> with high correlation coefficients up to 0.996. Super-high sensitivity with a low detection limit (0.0003 μg L<sup>−1</sup>) and excellent reproducibility (relative standard deviation ≤ 7.4 %) is demonstrated, superior to the pristine GP electrode and most known electrodes. This study expands a novel application for NOPs and an alternative straightforward approach for the rapid and reliable detection of heavy metal ions.</div></div>\",\"PeriodicalId\":392,\"journal\":{\"name\":\"Microporous and Mesoporous Materials\",\"volume\":\"395 \",\"pages\":\"Article 113685\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-05-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Microporous and Mesoporous Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387181125001994\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous and Mesoporous Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387181125001994","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Hierarchically structured nanoporous organic polymers as a rapid electrochemical platform for monitoring trace heavy metal ions
Rapid electrochemical monitoring and detection of toxic heavy metal ions using chemically modified carbon paste electrodes (CPEs) is of great importance, but the development of chemically stable and porous CPE substrates with unique sensing properties remains challenging. Here, we synthesized nine low-cost nanoporous organic polymer (NOP) matrices under mild CPE conditions and developed highly sensitive graphite powder (GP)@NOP composite electrodes for sensing of trace heavy metal ions. These NOP substrates have great potential for electrochemical sensing due to their large surface area, layered porosity and excellent stability. The electrochemical properties, dominated by the pore structures of the NOPs, are simply turned by regulating the nature of the building blocks and crosslinkers. The micropores facilitate highly sensitive and selective detection and the mesopores benefit mass transfer. Using GP@NOP complex electrodes, the concentrations of the analyte show linear relationship with the oxidation current peak values over a concentration range of 0.0010–0.012 μg L−1 with high correlation coefficients up to 0.996. Super-high sensitivity with a low detection limit (0.0003 μg L−1) and excellent reproducibility (relative standard deviation ≤ 7.4 %) is demonstrated, superior to the pristine GP electrode and most known electrodes. This study expands a novel application for NOPs and an alternative straightforward approach for the rapid and reliable detection of heavy metal ions.
期刊介绍:
Microporous and Mesoporous Materials covers novel and significant aspects of porous solids classified as either microporous (pore size up to 2 nm) or mesoporous (pore size 2 to 50 nm). The porosity should have a specific impact on the material properties or application. Typical examples are zeolites and zeolite-like materials, pillared materials, clathrasils and clathrates, carbon molecular sieves, ordered mesoporous materials, organic/inorganic porous hybrid materials, or porous metal oxides. Both natural and synthetic porous materials are within the scope of the journal.
Topics which are particularly of interest include:
All aspects of natural microporous and mesoporous solids
The synthesis of crystalline or amorphous porous materials
The physico-chemical characterization of microporous and mesoporous solids, especially spectroscopic and microscopic
The modification of microporous and mesoporous solids, for example by ion exchange or solid-state reactions
All topics related to diffusion of mobile species in the pores of microporous and mesoporous materials
Adsorption (and other separation techniques) using microporous or mesoporous adsorbents
Catalysis by microporous and mesoporous materials
Host/guest interactions
Theoretical chemistry and modelling of host/guest interactions
All topics related to the application of microporous and mesoporous materials in industrial catalysis, separation technology, environmental protection, electrochemistry, membranes, sensors, optical devices, etc.