一种用于光催化CO2还原反应甲醇产率原位检测的光纤传感器

IF 5.5 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Shihui Wang, Yuyao Lei, Chao He, Junhe Miao, Yang Liu, Quanhua Xie, Karimi-Maleh Hassan, Nianbing Zhong
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引用次数: 0

摘要

为了实现光催化还原CO2过程中甲醇产率的现场实时检测,我们开发了一种使用共聚物涂层光纤布拉格光栅的甲醇传感器。建立了传感器测量甲醇的理论模型。研究了甲醇选择性敏感材料及其厚度对传感器性能的影响。补偿了湿度和温度对传感器测量的干扰。制备了TiO2光催化剂,搭建了光催化反应器。利用所制备的传感器对光催化CO2还原过程中甲醇的产率进行了原位监测。结果表明,600 nm厚聚n -异丙基丙烯酰胺/聚甲基丙烯酸甲酯涂层的光纤光栅甲醇传感器具有灵敏度高、检出限低、响应速度快、恢复速度快、选择性高等特点。采用气相色谱仪和制备的光纤布拉格光栅甲醇传感器测定TiO2光催化还原CO2的甲醇生成率分别为1.42和1.53 μmol/g-cat·h,两种检测方法的误差为7.86%。这凸显了所开发的光纤布拉格光栅甲醇传感器在光催化还原CO2过程中实时原位检测甲醇产率的有效性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A fiber-optic sensor for in-situ detection of methanol production rate in photocatalytic CO2 reduction reaction

In the pursuit of achieving in-situ real-time detection of methanol production rate during the photocatalytic reduction of CO2, we developed a methanol sensor using a copolymer-coated fiber Bragg gratings. The theoretical model of methanol measurement by sensor was established. The effect of methanol-selective sensitive material and its thickness on the performance of the sensor were investigated. Humidity and temperature interference to sensor measurements was compensated. Furthermore, TiO2 photocatalyst was prepared and the photocatalytic reactor was constructed. The methanol production rate in the photocatalytic CO2 reduction process was monitored by the prepared sensor in-situ. The results highlight that the fiber Bragg grating methanol sensor with 600 nm-thick poly(N-isopropylacrylamide)/polymethyl-methacrylate coating showed a high sensitivity, lower limit of detection, fast response and recovery speed, and high selectivity. The methanol generation rate of TiO2 photocatalytic reduction of CO2 measured by gas chromatograph and prepared fiber Bragg grating methanol sensor was 1.42 and 1.53 μmol/g-cat·h, respectively, the error of the two detection methods was 7.86%. This highlights the efficacy of the developed fiber Bragg grating methanol sensor for real-time in-situ detection of the methanol production rate during the photocatalytic reduction of CO2.

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来源期刊
Carbon Letters
Carbon Letters CHEMISTRY, MULTIDISCIPLINARY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
7.30
自引率
20.00%
发文量
118
期刊介绍: Carbon Letters aims to be a comprehensive journal with complete coverage of carbon materials and carbon-rich molecules. These materials range from, but are not limited to, diamond and graphite through chars, semicokes, mesophase substances, carbon fibers, carbon nanotubes, graphenes, carbon blacks, activated carbons, pyrolytic carbons, glass-like carbons, etc. Papers on the secondary production of new carbon and composite materials from the above mentioned various carbons are within the scope of the journal. Papers on organic substances, including coals, will be considered only if the research has close relation to the resulting carbon materials. Carbon Letters also seeks to keep abreast of new developments in their specialist fields and to unite in finding alternative energy solutions to current issues such as the greenhouse effect and the depletion of the ozone layer. The renewable energy basics, energy storage and conversion, solar energy, wind energy, water energy, nuclear energy, biomass energy, hydrogen production technology, and other clean energy technologies are also within the scope of the journal. Carbon Letters invites original reports of fundamental research in all branches of the theory and practice of carbon science and technology.
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