通过调整阴离子和阳离子添加剂打破水电池锌阳极的性能限制

IF 26.6 1区材料科学 Q1 Engineering

Nano-Micro Letters Pub Date : 2025-05-19 DOI:10.1007/s40820-025-01773-6

Zhaoxu Mai, Yuexing Lin, Jingying Sun, Chenhui Wang, Gongzheng Yang, Chengxin Wang

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引用次数: 0

摘要

阳离子苯三乙基氯化铵通过选择性吸附使锌具有高（002）结构，优于先前的添加剂。原位均质化将商业锌箔转化为高度（002）织构的锌阳极而无需预处理。揭示了Cl−致点蚀机理，突破了锌阳极的性能极限。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Breaking Performance Limits of Zn Anodes in Aqueous Batteries by Tailoring Anion and Cation Additives

Highlights

Cationic benzyltriethylammonium chloride enables high (002)-textured Zn via selective adsorption, outperforming prior additives.
In situ homogenization converts commercial Zn foil into highly (002)-textured Zn anodes without pretreatments.
Cl⁻-induced pitting corrosion mechanism uncovered, leading to a breakthrough in performance limits of Zn anodes.

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来源期刊

Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY

CiteScore

32.60

自引率

4.90%

发文量

981

审稿时长

1.1 months

期刊介绍： Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.