介孔八面体层流结构作为锂硫电池的有效载体

IF 2.5 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Pai Lv, Xin-wei Wang, Jian Li, Yan-yang Duan, Chun-peng Hui, Shun-hua Wang
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引用次数: 0

摘要

为了在锂电池领域寻找合适的主机,创新一种负载充足S元素的主机具有重要意义。它为Li和S元素之间的相互作用提供了一个空间。同时防止中间多硫化物的溶解。本文报道了一种由钇(Y2O3)、硫和Ti3C2TF通过水热法和球磨法合成的突出的主体。这种结构可以及时圈闭和储存硫元素。通过综合这些优点,含硫63.42 wt%的复合材料具有突出的初始放电电容,在1 a g−1时具有1521.056 mAh g−1,循环1000次后仍具有1175.15 mAh g−1,与此相比,含碳纳米管(CNTs)的复合材料具有更大的初始放电电容1750.24 mAh g−1,经历1000次循环,仍具有1576.24 mAh g−1,每循环具有0.00995%的电容延迟,保持90.05%的保留率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mesoporous octahedron laminar structure as an effective host for Li-S batteries

For seeking an appropriate host in the fields of Li-S batteries, it is significant to innovate a host which load sufficient S element. It provides a space for interaction between Li and S elements. At meanwhile, it prevents the dissolution of intermediate polysulfides. In there, we report a prominent host that are synthesized by yttria (Y2O3), sulfur, and Ti3C2TF by the methods of hydrothermal method and ball milling method. This structure can entrap and store sulfur elements timely. By combing these merits, composite with 63.42 wt% sulfur arrive a prominent initial discharge capacitance, has 1521.056 mAh g− 1 at 1 A g− 1, after 1000 cycles, still has 1175.15 mAh g− 1, In comparison to this, composite with carbon nanotubes (CNTs) offers a greater initial discharge capacitance 1750.24 mAh g− 1, experiences with 1000 cycles, still has 1576.24 mAh g− 1, has 0.00995% capacitance delay per cycle, keeps 90.05% retention.

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来源期刊
Applied Physics A
Applied Physics A 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.40%
发文量
964
审稿时长
38 days
期刊介绍: Applied Physics A publishes experimental and theoretical investigations in applied physics as regular articles, rapid communications, and invited papers. The distinguished 30-member Board of Editors reflects the interdisciplinary approach of the journal and ensures the highest quality of peer review.
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