{"title":"V2O5掺杂nife层状双氢氧化物:能源和环境修复的双功能催化剂","authors":"Sakarapani Sarala, Palani Karthik, Velusamy Sasikala, Natarajan Prakash, Azhagurajan Mukkannan","doi":"10.1007/s11164-025-05582-9","DOIUrl":null,"url":null,"abstract":"<div><p>Addressing the dual challenges of sustainable energy production and environmental remediation, this research focuses on the development of V<sub>2</sub>O<sub>5</sub>-doped NiFe-layered double hydroxides (LDHs) for efficient water splitting and photocatalytic degradation of tetracycline. Utilizing a hydrothermal synthesis method, V<sub>2</sub>O<sub>5</sub>-doped NiFe-LDHs were successfully fabricated. The incorporation of V<sub>2</sub>O<sub>5</sub> aims to enhance the catalytic performance by introducing additional redox-active sites, boosting electronic conductivity, and stabilizing the LDH structure during operational cycles. Comprehensive characterization, including X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy, was employed to analyze the structural and morphological properties of the synthesized materials. Electrochemical studies demonstrated significant improvements in water splitting performance, including reduced overpotentials and enhanced hydrogen evolution rates. Additionally, the photocatalytic activity of V<sub>2</sub>O<sub>5</sub>-doped NiFe-LDHs for tetracycline degradation was evaluated, showing promising results for effective pollutant removal. These findings underscore the potential of V<sub>2</sub>O<sub>5</sub>-doped NiFe-LDHs as advanced materials for both clean energy production and environmental cleanup.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 6","pages":"2955 - 2979"},"PeriodicalIF":2.8000,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"V2O5 -doped NiFe-layered double hydroxides: bifunctional catalysts for energy and environmental remediation\",\"authors\":\"Sakarapani Sarala, Palani Karthik, Velusamy Sasikala, Natarajan Prakash, Azhagurajan Mukkannan\",\"doi\":\"10.1007/s11164-025-05582-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Addressing the dual challenges of sustainable energy production and environmental remediation, this research focuses on the development of V<sub>2</sub>O<sub>5</sub>-doped NiFe-layered double hydroxides (LDHs) for efficient water splitting and photocatalytic degradation of tetracycline. Utilizing a hydrothermal synthesis method, V<sub>2</sub>O<sub>5</sub>-doped NiFe-LDHs were successfully fabricated. The incorporation of V<sub>2</sub>O<sub>5</sub> aims to enhance the catalytic performance by introducing additional redox-active sites, boosting electronic conductivity, and stabilizing the LDH structure during operational cycles. Comprehensive characterization, including X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy, was employed to analyze the structural and morphological properties of the synthesized materials. Electrochemical studies demonstrated significant improvements in water splitting performance, including reduced overpotentials and enhanced hydrogen evolution rates. Additionally, the photocatalytic activity of V<sub>2</sub>O<sub>5</sub>-doped NiFe-LDHs for tetracycline degradation was evaluated, showing promising results for effective pollutant removal. These findings underscore the potential of V<sub>2</sub>O<sub>5</sub>-doped NiFe-LDHs as advanced materials for both clean energy production and environmental cleanup.</p></div>\",\"PeriodicalId\":753,\"journal\":{\"name\":\"Research on Chemical Intermediates\",\"volume\":\"51 6\",\"pages\":\"2955 - 2979\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Research on Chemical Intermediates\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11164-025-05582-9\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Research on Chemical Intermediates","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11164-025-05582-9","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
V2O5 -doped NiFe-layered double hydroxides: bifunctional catalysts for energy and environmental remediation
Addressing the dual challenges of sustainable energy production and environmental remediation, this research focuses on the development of V2O5-doped NiFe-layered double hydroxides (LDHs) for efficient water splitting and photocatalytic degradation of tetracycline. Utilizing a hydrothermal synthesis method, V2O5-doped NiFe-LDHs were successfully fabricated. The incorporation of V2O5 aims to enhance the catalytic performance by introducing additional redox-active sites, boosting electronic conductivity, and stabilizing the LDH structure during operational cycles. Comprehensive characterization, including X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy, was employed to analyze the structural and morphological properties of the synthesized materials. Electrochemical studies demonstrated significant improvements in water splitting performance, including reduced overpotentials and enhanced hydrogen evolution rates. Additionally, the photocatalytic activity of V2O5-doped NiFe-LDHs for tetracycline degradation was evaluated, showing promising results for effective pollutant removal. These findings underscore the potential of V2O5-doped NiFe-LDHs as advanced materials for both clean energy production and environmental cleanup.
期刊介绍:
Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry.
The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.