仲丁基苯的好氧液相氧化生成过氧化氢

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-05-15 DOI:10.1007/s11172-025-4594-6

E. A. Kurganova, V. S. Kabanova, G. N. Koshel, A. S. Frolov

{"title":"仲丁基苯的好氧液相氧化生成过氧化氢","authors":"E. A. Kurganova, V. S. Kabanova, G. N. Koshel, A. S. Frolov","doi":"10.1007/s11172-025-4594-6","DOIUrl":null,"url":null,"abstract":"<div><p>Aerobic liquid-phase oxidation of <i>sec</i>-butylbenzene to the hydroperoxide in the presence of initiators and organic catalysts and in the absence of any additives was studied. The influence of temperature, reaction time, and concentration and structure of the catalyst on the oxidation was examined. The use of <i>N</i>-hydroxyphthalimide as a catalyst was found to carry out the aerobic liquid-phase oxidation of <i>sec</i>-butylbenzene to the hydroperoxide with selectivity about 95% at a hydrocarbon conversion of 35–40% within 40–50 min.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"74 4","pages":"1001 - 1006"},"PeriodicalIF":1.7000,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Aerobic liquid-phase oxidation of sec-butylbenzene to the hydroperoxide\",\"authors\":\"E. A. Kurganova, V. S. Kabanova, G. N. Koshel, A. S. Frolov\",\"doi\":\"10.1007/s11172-025-4594-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Aerobic liquid-phase oxidation of <i>sec</i>-butylbenzene to the hydroperoxide in the presence of initiators and organic catalysts and in the absence of any additives was studied. The influence of temperature, reaction time, and concentration and structure of the catalyst on the oxidation was examined. The use of <i>N</i>-hydroxyphthalimide as a catalyst was found to carry out the aerobic liquid-phase oxidation of <i>sec</i>-butylbenzene to the hydroperoxide with selectivity about 95% at a hydrocarbon conversion of 35–40% within 40–50 min.</p></div>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":\"74 4\",\"pages\":\"1001 - 1006\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2025-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11172-025-4594-6\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-025-4594-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

研究了在有引发剂、有机催化剂和无添加剂的条件下，仲丁基苯的好氧液相氧化制过氧化氢的反应。考察了反应温度、反应时间、催化剂的浓度和结构对氧化反应的影响。采用n -羟基邻苯二胺作为催化剂，在40-50 min内，以35-40%的碳氢转化率，对正丁基苯进行了选择性约95%的好氧液相氧化制氢过氧化物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Aerobic liquid-phase oxidation of sec-butylbenzene to the hydroperoxide

Aerobic liquid-phase oxidation of sec-butylbenzene to the hydroperoxide in the presence of initiators and organic catalysts and in the absence of any additives was studied. The influence of temperature, reaction time, and concentration and structure of the catalyst on the oxidation was examined. The use of N-hydroxyphthalimide as a catalyst was found to carry out the aerobic liquid-phase oxidation of sec-butylbenzene to the hydroperoxide with selectivity about 95% at a hydrocarbon conversion of 35–40% within 40–50 min.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.