Laser Scribed CNTs/PEEK/TPU Composites Film for High-Performance Stretchable Electrodes

In this article, an elastic composite material comprising carbon nanotubes (CNTs), polyether-ether-ketone (PEEK), and thermoplastic polyurethane (TPU) is presented, in which direct laser-induced graphitization was used to fabricate high-performance stretchable electrodes. The introduction of CNTs can enhance the conductivity and mechanical strength of the composites, thus improving the overall performance of the sensors. Flexible strain sensors with porous structures were prepared by appropriate encapsulation methods, which exhibited superior gauge factors (GFs) of 72, 367, and 972 in the 0%–30%, 30%–44%, and 44%–53% strain regions, respectively. Furthermore, it features a rapid response time (100 ms), excellent stability and durability, and is capable of detecting both large-scale human movement and monitoring of small physical signals. In addition, patterned laser-induced graphene interdigital electrodes (LIG-IDEs) were fabricated on composites using laser light. Highly sensitive humidity sensors were obtained using graphene oxide as the humidity-sensing material for respiratory monitoring and noncontact sensing. The thermoplastic properties of TPU allow the straight fiber to be thermoformed into highly stretchable helical electrode, which was of a helix index of 5 and with a high-quality factor ( ${Q} =130$ ) at 1250% strain. In conclusion, the preparation of LIG on stretchable composite films by direct laser scribing shows a promising approach for large-scale fabrication of wearable devices.