用桥接N基离子液体合成六元N杂环化合物的研究进展

IF 2.8 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2025-05-01 DOI:10.1002/ajoc.202400785

Anvita Chaudhary , Richa Srivastava

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引用次数: 0

摘要

六元含氮杂环化合物是有机化学中一类重要的化合物，在许多领域发挥着关键作用。这些化合物的传统合成方法具有一定的优势，但也受到包括环境影响在内的许多因素的限制。含氮桥头碱类化合物，如六亚甲基四胺（HMTA）、1,5,7‐三氮杂环[4.4.0]十二烷- 5烯（TBD）、1,4‐重氮杂环[2.2.2]辛烷（DABCO）和1,8‐重氮杂环[5.4.0]二氮杂环-七烯（DBU）等，在开发特定任务离子液体方面表现出了良好的特性。这些离子液体已被用于合成六元含氮杂环化合物，符合绿色和可持续化学的原则。因此，本文汇编了利用桥头氮基离子液体合成六元含氮杂环化合物的最新进展。该手稿涵盖了2013年以后发表的研究。

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Synthetic Approaches of Six Membered N‐Heterocycles Using Bridged N‐Based Ionic Liquids: A Review

Six‐membered nitrogen‐containing heterocycles represent a significant class of compounds in organic chemistry and play a pivotal role in various fields. Conventional synthetic methods of these compounds have certain advantages, but they are also limited by many factors including environmental impacts. Nitrogen‐containing bridge‐head basic compounds like hexamethylenetetramine (HMTA), 1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (TBD), 1,4‐diazabicyclo[2.2.2]octane (DABCO), and 1,8‐diazabicyclo‐[5.4.0]undec‐7‐ene (DBU) have shown promising characteristics in developing task‐specific ionic liquids. These ionic liquids have been employed in synthesizing six‐membered nitrogen‐containing heterocyclic compounds in accordance with the principles of green and sustainable chemistry. Hence, this manuscript has been compiled on recent developments in the synthesis of six‐membered nitrogen‐containing heterocycles using bridge‐head nitrogen‐based ionic liquids. The manuscript covers studies published from 2013 onwards.

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.