Seyed Mohammad Hossein Mousavian, Vasily Anatolievich Bautin
{"title":"可充电镁电池:克服高效能源应用的挑战","authors":"Seyed Mohammad Hossein Mousavian, Vasily Anatolievich Bautin","doi":"10.1016/j.est.2025.117079","DOIUrl":null,"url":null,"abstract":"<div><div>Rechargeable magnesium batteries (RMBs) are gaining attention as a viable alternative to lithium-ion batteries, leveraging magnesium’s high volumetric capacity (3833 mAh/cm<sup>3</sup>), inherent safety due to dendrite-free operation, and cost-effectiveness stemming from its abundance. This comprehensive review explores the electrochemical fundamentals, recent material advancements, performance characteristics, key technical hurdles, and prospective applications of RMBs. Despite their promising theoretical advantages, practical implementation is impeded by challenges such as sluggish Mg<sup>2+</sup> diffusion, anode passivation, and limited cathode-electrolyte compatibility. Innovations like nanostructured cathodes (e.g., Cu<sub>2</sub>S, Mo<sub>3</sub>S<sub>13</sub>), stable electrolytes (e.g., Mg(TFSI)<sub>2</sub>-based systems), and hybrid Mg<img>Li designs address these barriers. Potential applications span electric vehicles, grid-scale energy storage, aerospace, and portable electronics. Advances driven by artificial intelligence (AI) and sophisticated material engineering may accelerate their commercialization. This review highlights RMBs' potential to revolutionize sustainable energy storage and outlines a strategic roadmap for future research and industrial adoption.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"126 ","pages":"Article 117079"},"PeriodicalIF":8.9000,"publicationDate":"2025-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rechargeable magnesium batteries: Overcoming challenges for high-efficiency energy applications\",\"authors\":\"Seyed Mohammad Hossein Mousavian, Vasily Anatolievich Bautin\",\"doi\":\"10.1016/j.est.2025.117079\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Rechargeable magnesium batteries (RMBs) are gaining attention as a viable alternative to lithium-ion batteries, leveraging magnesium’s high volumetric capacity (3833 mAh/cm<sup>3</sup>), inherent safety due to dendrite-free operation, and cost-effectiveness stemming from its abundance. This comprehensive review explores the electrochemical fundamentals, recent material advancements, performance characteristics, key technical hurdles, and prospective applications of RMBs. Despite their promising theoretical advantages, practical implementation is impeded by challenges such as sluggish Mg<sup>2+</sup> diffusion, anode passivation, and limited cathode-electrolyte compatibility. Innovations like nanostructured cathodes (e.g., Cu<sub>2</sub>S, Mo<sub>3</sub>S<sub>13</sub>), stable electrolytes (e.g., Mg(TFSI)<sub>2</sub>-based systems), and hybrid Mg<img>Li designs address these barriers. Potential applications span electric vehicles, grid-scale energy storage, aerospace, and portable electronics. Advances driven by artificial intelligence (AI) and sophisticated material engineering may accelerate their commercialization. This review highlights RMBs' potential to revolutionize sustainable energy storage and outlines a strategic roadmap for future research and industrial adoption.</div></div>\",\"PeriodicalId\":15942,\"journal\":{\"name\":\"Journal of energy storage\",\"volume\":\"126 \",\"pages\":\"Article 117079\"},\"PeriodicalIF\":8.9000,\"publicationDate\":\"2025-05-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of energy storage\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352152X2501792X\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of energy storage","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352152X2501792X","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Rechargeable magnesium batteries: Overcoming challenges for high-efficiency energy applications
Rechargeable magnesium batteries (RMBs) are gaining attention as a viable alternative to lithium-ion batteries, leveraging magnesium’s high volumetric capacity (3833 mAh/cm3), inherent safety due to dendrite-free operation, and cost-effectiveness stemming from its abundance. This comprehensive review explores the electrochemical fundamentals, recent material advancements, performance characteristics, key technical hurdles, and prospective applications of RMBs. Despite their promising theoretical advantages, practical implementation is impeded by challenges such as sluggish Mg2+ diffusion, anode passivation, and limited cathode-electrolyte compatibility. Innovations like nanostructured cathodes (e.g., Cu2S, Mo3S13), stable electrolytes (e.g., Mg(TFSI)2-based systems), and hybrid MgLi designs address these barriers. Potential applications span electric vehicles, grid-scale energy storage, aerospace, and portable electronics. Advances driven by artificial intelligence (AI) and sophisticated material engineering may accelerate their commercialization. This review highlights RMBs' potential to revolutionize sustainable energy storage and outlines a strategic roadmap for future research and industrial adoption.
期刊介绍:
Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.