可充电镁电池:克服高效能源应用的挑战

IF 8.9 2区 工程技术 Q1 ENERGY & FUELS
Seyed Mohammad Hossein Mousavian, Vasily Anatolievich Bautin
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引用次数: 0

摘要

可充电镁电池(RMBs)作为锂离子电池的一种可行替代品,正受到越来越多的关注,因为它利用了镁的高容量(3833 mAh/cm3)、无枝晶操作的固有安全性以及丰富的成本效益。本文综述了电化学的基本原理、材料的最新进展、性能特点、关键技术障碍和前景应用。尽管它们具有很好的理论优势,但实际实施受到诸如Mg2+扩散缓慢、阳极钝化和阴极-电解质兼容性有限等挑战的阻碍。纳米结构阴极(如Cu2S、Mo3S13)、稳定电解质(如基于Mg(TFSI)2的系统)和混合MgLi设计等创新解决了这些障碍。潜在的应用领域包括电动汽车、电网规模的能源存储、航空航天和便携式电子产品。人工智能(AI)和复杂材料工程推动的进步可能会加速它们的商业化。这篇综述强调了RMBs在革新可持续能源存储方面的潜力,并概述了未来研究和工业应用的战略路线图。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Rechargeable magnesium batteries: Overcoming challenges for high-efficiency energy applications
Rechargeable magnesium batteries (RMBs) are gaining attention as a viable alternative to lithium-ion batteries, leveraging magnesium’s high volumetric capacity (3833 mAh/cm3), inherent safety due to dendrite-free operation, and cost-effectiveness stemming from its abundance. This comprehensive review explores the electrochemical fundamentals, recent material advancements, performance characteristics, key technical hurdles, and prospective applications of RMBs. Despite their promising theoretical advantages, practical implementation is impeded by challenges such as sluggish Mg2+ diffusion, anode passivation, and limited cathode-electrolyte compatibility. Innovations like nanostructured cathodes (e.g., Cu2S, Mo3S13), stable electrolytes (e.g., Mg(TFSI)2-based systems), and hybrid MgLi designs address these barriers. Potential applications span electric vehicles, grid-scale energy storage, aerospace, and portable electronics. Advances driven by artificial intelligence (AI) and sophisticated material engineering may accelerate their commercialization. This review highlights RMBs' potential to revolutionize sustainable energy storage and outlines a strategic roadmap for future research and industrial adoption.
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来源期刊
Journal of energy storage
Journal of energy storage Energy-Renewable Energy, Sustainability and the Environment
CiteScore
11.80
自引率
24.50%
发文量
2262
审稿时长
69 days
期刊介绍: Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.
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