金属间化合物对铝合金表面织构透膜电化学微加工的影响

IF 5.3 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS
Andrea Cristoforetti , Matteo Gamba , Andrea Brenna , Marco Ormellese , Michele Fedel
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引用次数: 0

摘要

金属表面织构是一项涉及电子、能量转换和流体动力学等广泛领域的关键技术。从鲨鱼皮肤上的条纹等生物结构中获得灵感,通过最小化漩涡形成来减少流体阻力的能力,工程纹理表面引起了极大的关注。尽管有这种兴趣,传统的制造方法,如聚合物涂层和增材制造,由于机械降解,往往面临耐久性的限制,导致高维护需求和长期效率降低。在这项研究中,通过掩膜电化学微加工(TMEMM)作为一种低损伤的技术,在铝合金,特别是AA1050, AA5005-H24和AA2024-T3上制造微结构进行了探索。TMEMM包括喷墨沉积绝缘掩膜,然后通过阳极极化在暴露的金属区域蚀刻精确的微特征。扫描电子显微镜揭示了蚀刻过程中几何参数的动态演变,为其进展提供了关键的见解。动电位极化评价进一步阐明了合金在蚀刻后和蚀刻过程中的电化学行为,显示了金属间颗粒和表面织构如何影响耐蚀性和反应性。这项研究强调了TMEMM在增强表面功能方面的潜力,同时解决了合金特有的挑战,为在各种技术领域推进纹理表面提供了见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of intermetallics on through-mask electrochemical micromachining for surface texturing of aluminum alloys
Metallic surface texturing is a key technique across a wide range of fields, including electronics, energy conversion, and fluid dynamics. Drawing inspiration from biological structures like the riblets on shark skin, known for their ability to reduce fluid drag by minimizing vortex formation, engineered textured surfaces have attracted significant attention. Despite this interest, conventional fabrication methods, such as polymeric coatings and additive manufacturing, often face limitations in durability due to mechanical degradation, resulting in high maintenance demands and reduced long-term efficiency. In this study, Through-Mask Electrochemical Micromachining (TMEMM) as a low-damage technique for fabricating microstructures on aluminum alloys, specifically AA1050, AA5005-H24, and AA2024-T3, was explored. TMEMM involves the ink-jet deposition of an insulating mask, followed by anodic polarization to etch precise microfeatures in the exposed metallic areas. Scanning electron microscopy reveals the dynamic evolution of geometric parameters during the etching process, providing critical insights into its progression. Potentiodynamic polarization evaluations further clarify the electrochemical behavior of the alloys post and during etching, showing how intermetallic particles and surface texture influence corrosion resistance and reactivity. This study underscores TMEMM's potential in enhancing surface functionalities while addressing alloy-specific challenges, offering insights for advancing textured surfaces in various technological domains.
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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