Zeinhom M. El-Bahy , Taghrid S. Alomar , Najla AlMasoud , Muhammad Abdullah , Tehreem Zahra , Amal A. Al-wallan , Hafiz Muhammad Tahir Farid
{"title":"提高NdCoO3/rGO在析氧反应中的电催化性能","authors":"Zeinhom M. El-Bahy , Taghrid S. Alomar , Najla AlMasoud , Muhammad Abdullah , Tehreem Zahra , Amal A. Al-wallan , Hafiz Muhammad Tahir Farid","doi":"10.1016/j.chemphys.2025.112774","DOIUrl":null,"url":null,"abstract":"<div><div>An important concern in present research is the enhancement of an electrochemical water oxidation mechanism that can produce clean energy in a more cost-effective, efficient and reliable manner. A key aspect of this study is the generation of electrocatalysts that are both affordable and long-lasting. Cost-effective metal oxides are more advantageous than other media for the oxygen evolution reaction (OER) in basic electrolytes. Due to their impressive electrical properties and the potential for enhanced performance, perovskite-based composites have become highly valuable for the water oxidation reaction. In this report, we described the synthesis of rGO@NdCoO<sub>3</sub> using a sonication process employed toward the OER process. Furthermore, the rGO@NdCoO<sub>3</sub> composite demonstrated a very favorable overpotential (η) of 216 mV at current density (C<sub>d</sub>) of 10 mA/cm<sup>2</sup> and decreased Tafel slope (39 mV/dec). It remains durable for 35 h and even after going through 2000<sup>th</sup> cycles. The composite of rGO@NdCoO<sub>3</sub> demonstrated various advantageous effects, such as decreased overpotential, enhanced catalytic C<sub>d</sub>, improved charge transfer kinetics and increased ECSA value of 581.25 cm<sup>2</sup>. Based on the research, it is evident that the fabricated material demonstrated exceptional efficiency and durability as an electrocatalyst in energy conversion systems.</div></div>","PeriodicalId":272,"journal":{"name":"Chemical Physics","volume":"596 ","pages":"Article 112774"},"PeriodicalIF":2.0000,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improved electrocatalytic performance of NdCoO3/rGO for oxygen evolution reaction\",\"authors\":\"Zeinhom M. El-Bahy , Taghrid S. Alomar , Najla AlMasoud , Muhammad Abdullah , Tehreem Zahra , Amal A. Al-wallan , Hafiz Muhammad Tahir Farid\",\"doi\":\"10.1016/j.chemphys.2025.112774\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>An important concern in present research is the enhancement of an electrochemical water oxidation mechanism that can produce clean energy in a more cost-effective, efficient and reliable manner. A key aspect of this study is the generation of electrocatalysts that are both affordable and long-lasting. Cost-effective metal oxides are more advantageous than other media for the oxygen evolution reaction (OER) in basic electrolytes. Due to their impressive electrical properties and the potential for enhanced performance, perovskite-based composites have become highly valuable for the water oxidation reaction. In this report, we described the synthesis of rGO@NdCoO<sub>3</sub> using a sonication process employed toward the OER process. Furthermore, the rGO@NdCoO<sub>3</sub> composite demonstrated a very favorable overpotential (η) of 216 mV at current density (C<sub>d</sub>) of 10 mA/cm<sup>2</sup> and decreased Tafel slope (39 mV/dec). It remains durable for 35 h and even after going through 2000<sup>th</sup> cycles. The composite of rGO@NdCoO<sub>3</sub> demonstrated various advantageous effects, such as decreased overpotential, enhanced catalytic C<sub>d</sub>, improved charge transfer kinetics and increased ECSA value of 581.25 cm<sup>2</sup>. Based on the research, it is evident that the fabricated material demonstrated exceptional efficiency and durability as an electrocatalyst in energy conversion systems.</div></div>\",\"PeriodicalId\":272,\"journal\":{\"name\":\"Chemical Physics\",\"volume\":\"596 \",\"pages\":\"Article 112774\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2025-05-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Physics\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0301010425001752\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0301010425001752","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Improved electrocatalytic performance of NdCoO3/rGO for oxygen evolution reaction
An important concern in present research is the enhancement of an electrochemical water oxidation mechanism that can produce clean energy in a more cost-effective, efficient and reliable manner. A key aspect of this study is the generation of electrocatalysts that are both affordable and long-lasting. Cost-effective metal oxides are more advantageous than other media for the oxygen evolution reaction (OER) in basic electrolytes. Due to their impressive electrical properties and the potential for enhanced performance, perovskite-based composites have become highly valuable for the water oxidation reaction. In this report, we described the synthesis of rGO@NdCoO3 using a sonication process employed toward the OER process. Furthermore, the rGO@NdCoO3 composite demonstrated a very favorable overpotential (η) of 216 mV at current density (Cd) of 10 mA/cm2 and decreased Tafel slope (39 mV/dec). It remains durable for 35 h and even after going through 2000th cycles. The composite of rGO@NdCoO3 demonstrated various advantageous effects, such as decreased overpotential, enhanced catalytic Cd, improved charge transfer kinetics and increased ECSA value of 581.25 cm2. Based on the research, it is evident that the fabricated material demonstrated exceptional efficiency and durability as an electrocatalyst in energy conversion systems.
期刊介绍:
Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.