提高NdCoO3/rGO在析氧反应中的电催化性能

IF 2 3区 化学 Q4 CHEMISTRY, PHYSICAL
Zeinhom M. El-Bahy , Taghrid S. Alomar , Najla AlMasoud , Muhammad Abdullah , Tehreem Zahra , Amal A. Al-wallan , Hafiz Muhammad Tahir Farid
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引用次数: 0

摘要

目前研究的一个重要问题是加强电化学水氧化机制,以更经济、高效和可靠的方式生产清洁能源。这项研究的一个关键方面是产生既便宜又持久的电催化剂。低成本的金属氧化物比其他介质更有利于碱性电解质中的析氧反应。由于其令人印象深刻的电性能和增强性能的潜力,钙钛矿基复合材料在水氧化反应中变得非常有价值。在本报告中,我们描述了使用OER过程中采用的超声过程合成rGO@NdCoO3。此外,rGO@NdCoO3复合材料在电流密度(Cd)为10 mA/cm2时的过电位(η)为216 mV, Tafel斜率(39 mV/dec)减小。它仍然耐用35小时,甚至经过2000次循环。rGO@NdCoO3复合材料表现出降低过电位、增强催化Cd、改善电荷转移动力学和提高ECSA值581.25 cm2等多种有利效果。基于研究,很明显,所制备的材料在能量转换系统中作为电催化剂表现出卓越的效率和耐久性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improved electrocatalytic performance of NdCoO3/rGO for oxygen evolution reaction
An important concern in present research is the enhancement of an electrochemical water oxidation mechanism that can produce clean energy in a more cost-effective, efficient and reliable manner. A key aspect of this study is the generation of electrocatalysts that are both affordable and long-lasting. Cost-effective metal oxides are more advantageous than other media for the oxygen evolution reaction (OER) in basic electrolytes. Due to their impressive electrical properties and the potential for enhanced performance, perovskite-based composites have become highly valuable for the water oxidation reaction. In this report, we described the synthesis of rGO@NdCoO3 using a sonication process employed toward the OER process. Furthermore, the rGO@NdCoO3 composite demonstrated a very favorable overpotential (η) of 216 mV at current density (Cd) of 10 mA/cm2 and decreased Tafel slope (39 mV/dec). It remains durable for 35 h and even after going through 2000th cycles. The composite of rGO@NdCoO3 demonstrated various advantageous effects, such as decreased overpotential, enhanced catalytic Cd, improved charge transfer kinetics and increased ECSA value of 581.25 cm2. Based on the research, it is evident that the fabricated material demonstrated exceptional efficiency and durability as an electrocatalyst in energy conversion systems.
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来源期刊
Chemical Physics
Chemical Physics 化学-物理:原子、分子和化学物理
CiteScore
4.60
自引率
4.30%
发文量
278
审稿时长
39 days
期刊介绍: Chemical Physics publishes experimental and theoretical papers on all aspects of chemical physics. In this journal, experiments are related to theory, and in turn theoretical papers are related to present or future experiments. Subjects covered include: spectroscopy and molecular structure, interacting systems, relaxation phenomena, biological systems, materials, fundamental problems in molecular reactivity, molecular quantum theory and statistical mechanics. Computational chemistry studies of routine character are not appropriate for this journal.
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