用胺醚作为新型捕收剂在弱碱性条件下浮选分离石英和长石

IF 4.1 2区 工程技术 Q2 ENGINEERING, CHEMICAL
Xinyan Suo, Bowen Yu, Jinting Sha, Runbo Gao, Mengyao Qi, Yehao Huang, Weijun Peng, Xiao Guo, Wei Wang, Yijun Cao, Chongqing Wang, Yukun Huang
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引用次数: 0

摘要

在弱碱性条件下,将胺醚作为一种新型捕收剂用于石英的直接浮选,实现了石英与长石的分离。浮选结果表明,石英和长石的回收率差异随着胺醚碳链长度和烷氧基数目的增加而减小。以十二胺聚氧乙烯醚(AC1210)为捕收剂,在矿浆pH为8.0的条件下,两者的回收率相差近90 %。机理分析结果表明,AC1210通过静电相互作用和氢键作用有效吸附在石英表面。然而,长石表面的K+与AC1210带正电的NH+基团之间的静电斥力削弱了AC1210在长石表面的吸附作用。石英和长石对AC1210吸附量的差异促进了石英和长石混合物中石英的选择性正浮选。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Flotation separation of quartz and feldspar under weak alkaline conditions using amine ether as a novel collector

Flotation separation of quartz and feldspar under weak alkaline conditions using amine ether as a novel collector
Amine ether was initially used as a novel collector for the direct flotation of quartz to separate the quartz from feldspar under weak alkaline conditions. The flotation results demonstrated that the recovery differences between quartz and feldspar both decreased with the increase in the carbon chain length and number of alkoxy groups of amine ether. A recovery difference of nearly 90 % could be achieved between them at a pulp pH of 8.0 with dodecylamine polyoxyethylene ether (AC1210) serving as the collector. The results of the mechanism analysis demonstrated that AC1210 was effectively adsorbed on the quartz surface via electrostatic interaction and hydrogen bonding. However, the electrostatic repulsion between the K+ on the feldspar surface and positively charged NH+ groups of AC1210 weakened the adsorption of AC1210 on the surface of feldspar. The difference in the adsorption capacity of AC1210 between the quartz and feldspar promoted the selective direct flotation of quartz from the mixture of quartz and feldspar.
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来源期刊
Chemical Engineering Science
Chemical Engineering Science 工程技术-工程:化工
CiteScore
7.50
自引率
8.50%
发文量
1025
审稿时长
50 days
期刊介绍: Chemical engineering enables the transformation of natural resources and energy into useful products for society. It draws on and applies natural sciences, mathematics and economics, and has developed fundamental engineering science that underpins the discipline. Chemical Engineering Science (CES) has been publishing papers on the fundamentals of chemical engineering since 1951. CES is the platform where the most significant advances in the discipline have ever since been published. Chemical Engineering Science has accompanied and sustained chemical engineering through its development into the vibrant and broad scientific discipline it is today.
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