Kenji Takada, Joe Komeda, Hiroaki Maeda, Naoya Fukui, Hiroyasu Masunaga, Sono Sasaki, Hiroshi Nishihara
{"title":"电功能二维双（三吡啶）铜（II）聚合物纳米片的界面合成。","authors":"Kenji Takada, Joe Komeda, Hiroaki Maeda, Naoya Fukui, Hiroyasu Masunaga, Sono Sasaki, Hiroshi Nishihara","doi":"10.3390/molecules30092044","DOIUrl":null,"url":null,"abstract":"<p><p>Coordination polymers are attractive materials for various fields of practical application. The high degree of freedom of choice of metal ions and organic ligands plays a critical role in functional diversification. In the present study, we report the liquid-liquid interfacial synthesis of a 2D bis(terpyridine)copper(II) polymer thin film, Cu-tpy. The synthesized Cu-tpy was characterized by various microscopic observations such as TEM, SEM, and AFM, and spectroscopic measurements such as XPS, Raman spectroscopy, SEM/EDS, and UV-Vis spectroscopy. Synchrotron-radiated X-ray scattering confirmed that Cu-tpy was oriented crystalline films. Moreover, Cu-tpy showed electrochemical micro-supercapacitor behavior in the solid-state owing to its ionic nature. This study expands the potential of bis(terpyridine)metal(II) polymers as electro-functional materials.</p>","PeriodicalId":19041,"journal":{"name":"Molecules","volume":"30 9","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12073553/pdf/","citationCount":"0","resultStr":"{\"title\":\"Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet.\",\"authors\":\"Kenji Takada, Joe Komeda, Hiroaki Maeda, Naoya Fukui, Hiroyasu Masunaga, Sono Sasaki, Hiroshi Nishihara\",\"doi\":\"10.3390/molecules30092044\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Coordination polymers are attractive materials for various fields of practical application. The high degree of freedom of choice of metal ions and organic ligands plays a critical role in functional diversification. In the present study, we report the liquid-liquid interfacial synthesis of a 2D bis(terpyridine)copper(II) polymer thin film, Cu-tpy. The synthesized Cu-tpy was characterized by various microscopic observations such as TEM, SEM, and AFM, and spectroscopic measurements such as XPS, Raman spectroscopy, SEM/EDS, and UV-Vis spectroscopy. Synchrotron-radiated X-ray scattering confirmed that Cu-tpy was oriented crystalline films. Moreover, Cu-tpy showed electrochemical micro-supercapacitor behavior in the solid-state owing to its ionic nature. This study expands the potential of bis(terpyridine)metal(II) polymers as electro-functional materials.</p>\",\"PeriodicalId\":19041,\"journal\":{\"name\":\"Molecules\",\"volume\":\"30 9\",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-05-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12073553/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Molecules\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.3390/molecules30092044\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMISTRY & MOLECULAR BIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molecules","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.3390/molecules30092044","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}
Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet.
Coordination polymers are attractive materials for various fields of practical application. The high degree of freedom of choice of metal ions and organic ligands plays a critical role in functional diversification. In the present study, we report the liquid-liquid interfacial synthesis of a 2D bis(terpyridine)copper(II) polymer thin film, Cu-tpy. The synthesized Cu-tpy was characterized by various microscopic observations such as TEM, SEM, and AFM, and spectroscopic measurements such as XPS, Raman spectroscopy, SEM/EDS, and UV-Vis spectroscopy. Synchrotron-radiated X-ray scattering confirmed that Cu-tpy was oriented crystalline films. Moreover, Cu-tpy showed electrochemical micro-supercapacitor behavior in the solid-state owing to its ionic nature. This study expands the potential of bis(terpyridine)metal(II) polymers as electro-functional materials.
期刊介绍：
Molecules (ISSN 1420-3049, CODEN: MOLEFW) is an open access journal of synthetic organic chemistry and natural product chemistry. All articles are peer-reviewed and published continously upon acceptance. Molecules is published by MDPI, Basel, Switzerland. Our aim is to encourage chemists to publish as much as possible their experimental detail, particularly synthetic procedures and characterization information. There is no restriction on the length of the experimental section. In addition, availability of compound samples is published and considered as important information. Authors are encouraged to register or deposit their chemical samples through the non-profit international organization Molecular Diversity Preservation International (MDPI). Molecules has been launched in 1996 to preserve and exploit molecular diversity of both, chemical information and chemical substances.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
