三元熔体中颗粒的生长。

IF 3.1 2区化学 Q3 CHEMISTRY, PHYSICAL

Journal of Chemical Physics Pub Date : 2025-05-07 DOI:10.1063/5.0255527

M L Zhang, M W Chen, N Liu, C M Yang, Z D Wang

{"title":"三元熔体中颗粒的生长。","authors":"M L Zhang, M W Chen, N Liu, C M Yang, Z D Wang","doi":"10.1063/5.0255527","DOIUrl":null,"url":null,"abstract":"The growth of particles in the ternary melt considering solute interactions is investigated employing the asymptotic method. The asymptotic solution of the dynamic model of the particle reveals the significant influence of solute interactions on the growth and interface morphology in the ternary alloy melt. The attractive interaction between the solutes causes the interface concentration of the major solute decrease, while that of the minor solute increase, the interface temperature decrease, and particle growth decelerate. By contrast, the repulsive interaction between the solutes causes the interface concentration of the major solute increase, while that of the minor solute decrease, and the interface temperature increases, and the particle growth accelerates. The solute interactions in the ternary alloy melt may make the particle evolve into complex interfacial patterns.","PeriodicalId":15313,"journal":{"name":"Journal of Chemical Physics","volume":"162 17","pages":""},"PeriodicalIF":3.1000,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Growth of particles in a ternary melt.\",\"authors\":\"M L Zhang, M W Chen, N Liu, C M Yang, Z D Wang\",\"doi\":\"10.1063/5.0255527\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The growth of particles in the ternary melt considering solute interactions is investigated employing the asymptotic method. The asymptotic solution of the dynamic model of the particle reveals the significant influence of solute interactions on the growth and interface morphology in the ternary alloy melt. The attractive interaction between the solutes causes the interface concentration of the major solute decrease, while that of the minor solute increase, the interface temperature decrease, and particle growth decelerate. By contrast, the repulsive interaction between the solutes causes the interface concentration of the major solute increase, while that of the minor solute decrease, and the interface temperature increases, and the particle growth accelerates. The solute interactions in the ternary alloy melt may make the particle evolve into complex interfacial patterns.\",\"PeriodicalId\":15313,\"journal\":{\"name\":\"Journal of Chemical Physics\",\"volume\":\"162 17\",\"pages\":\"\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2025-05-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Physics\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1063/5.0255527\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Physics","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1063/5.0255527","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

采用渐近方法研究了溶质相互作用下三元熔体中粒子的生长。粒子动力学模型的渐近解揭示了溶质相互作用对三元合金熔体生长和界面形貌的显著影响。由于溶质间的相互吸引作用，导致主溶质界面浓度降低，次溶质界面浓度升高，界面温度降低，颗粒生长减慢。而溶质间的排斥性相互作用导致主溶质界面浓度升高，次溶质界面浓度降低，界面温度升高，颗粒生长加速。三元合金熔体中溶质的相互作用可使颗粒演化成复杂的界面图案。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Growth of particles in a ternary melt.

The growth of particles in the ternary melt considering solute interactions is investigated employing the asymptotic method. The asymptotic solution of the dynamic model of the particle reveals the significant influence of solute interactions on the growth and interface morphology in the ternary alloy melt. The attractive interaction between the solutes causes the interface concentration of the major solute decrease, while that of the minor solute increase, the interface temperature decrease, and particle growth decelerate. By contrast, the repulsive interaction between the solutes causes the interface concentration of the major solute increase, while that of the minor solute decrease, and the interface temperature increases, and the particle growth accelerates. The solute interactions in the ternary alloy melt may make the particle evolve into complex interfacial patterns.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Chemical Physics 物理-物理：原子、分子和化学物理

CiteScore

7.40

自引率

15.90%

发文量

1615

审稿时长

2 months

期刊介绍： The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.