[食物垃圾高温预处理堆肥修复镉铅污染土壤的潜力及机理]。

Q2 Environmental Science
Lin-Pei Han, Lei Li, Xin-Yi Xu, Wen-Jie Ye, Yun Xu, Yi-Lu Gu, Xu-Ya Peng
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引用次数: 0

摘要

为探讨食物垃圾高温预处理堆肥对镉、铅污染土壤的修复潜力,将经过高温预处理堆肥(HC)、传统堆肥(TC)和仅高温预处理的食物垃圾与无机钝化剂(石灰/沸石)联合进行室内钝化培养实验。结果表明,HC与无机钝化剂组合(HLZ)对土壤中Cd和Pb的钝化效果最好,钝化率分别为76.92%和86.29%。土壤中Cd和Pb残留量比对照(CK)分别提高了10.65%和19.94%。傅里叶变换红外光谱分析表明,高温预处理可以促进好氧堆肥过程中有机物的降解,从而提高有机肥的腐殖质化程度。结果,生成的羧酸和羟基化合物能够与更多的Cd和Pb离子络合,降低了它们的生物利用度和迁移率。HLZ组土壤pH和电导率(EC)分别显著提高28.23%和23.80% (P<0.05)。速效氮、磷、钾养分含量最高(分别是对照的1.62、2.94和1.34倍),脲酶、过氧化氢酶、蔗糖酶和磷酸酶活性最高(分别是对照的7.17、2.09、1.83和8.36倍)。磷酸酶活性与镉、铅钝化率呈正相关(P<0.05)。HLZ组具有较高的磷酸酶活性(23.83 mg·g-1·d-1),在钝化重金属Cd、Pb和改善土壤生态功能方面具有较大的潜力。土壤理化指标的冗余分析和重金属的钝化效应表明,土壤pH、速效氮、有机质和EC显著影响Cd和Pb组分的转化(P<0.01)。HLZ组土壤pH、有效氮、有机质和EC均较高,其中有效氮含量和EC水平显著高于其他处理组(P<0.05),这可能是HLZ在镉、铅污染土壤修复中具有最佳潜力的主要原因。本研究为食物垃圾高温预处理堆肥产品及重金属污染土壤的修复提供了可行的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[Potential and Mechanism of High-temperature Pretreatment Composting of Food Waste for Amendment of Cadmium and Lead-contaminated Soil].

To investigate the potential of high-temperature pretreatment composting of food waste for the amendment of cadmium (Cd) and lead (Pb)-contaminated soil, food waste subjected to high-temperature pretreatment composting (HC), traditional composting (TC), and only high-temperature pretreatment were combined with inorganic passivators (lime/zeolite) for an indoor passivation cultivation experiment. The results indicated that HC combined with the inorganic passivators group (HLZ) exhibited the most effective passivation potential for Cd and Pb in soil, achieving passivation rates of 76.92% and 86.29%, respectively. Additionally, the residual fraction of Cd and Pb in the soil increased by 10.65% and 19.94% compared to that of the control group (CK). Fourier transform infrared spectroscopy analysis revealed that high-temperature pretreatment could facilitate the degradation of organic matter during aerobic composting, thereby improving the humification degree of organic fertilizer. As a result, the produced carboxylic acids and hydroxyl compounds were able to complex with more Cd and Pb ions, reducing their bioavailability and mobility. Moreover, the pH and electrical conductivity (EC) of the soil in the HLZ group significantly increased by 28.23% and 23.80%, respectively (P<0.05). Furthermore, the HLZ group exhibited the highest levels of available nitrogen, phosphorus, and potassium nutrients (1.62, 2.94, and 1.34 times higher than in CK), as well as activities of urease, hydrogen peroxide enzyme, sucrase enzyme, and phosphatase enzyme (7.17, 2.09, 1.83, and 8.36 times higher than in CK). Notably, phosphatase activity was positively correlated with the passivation rates of Cd and Pb (P<0.05). The HLZ group, characterized by high phosphatase activity (23.83 mg·g-1·d-1), exhibited greater potential in passivating heavy metals Cd and Pb and improving soil ecological functions. Redundancy analysis of soil physicochemical indicators and the passivation effect of heavy metals indicated that soil pH, available nitrogen, organic matter, and EC significantly influenced the transformation of Cd and Pb fractions (P<0.01). The soil in the HLZ group possessed high pH, effective nitrogen, organic matter, and EC and particularly significantly higher levels of effective nitrogen content and EC compared to those in other treatment groups (P<0.05), which could be the primary reason for the optimal potential of HLZ in the amendment of Cd and Pb-contaminated soils. This study provides a feasible application of high-temperature pretreatment compost products from food waste and the amendment of heavy metal-contaminated soil.

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环境科学
环境科学 Environmental Science-Environmental Science (all)
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