Electrocatalytic PANI-Encapsulated Aluminum Silicate/Ceramic Membranes for Efficient and Energy-Saving Removal of 4-Chlorophenol in Wastewater.

The removal of chlorinated organic pollutants from wastewater is a critical environmental challenge, as traditional methods for treating toxic pollutants like phenol and chlorophenols often suffer from high energy consumption and long treatment times, limiting their practical use. Electrocatalytic filtration has emerged as a promising alternative, but efficient, energy-saving electrocatalytic membranes for pollutants like 4-chlorophenol (4-CP) are still underexplored. A new type of electrocatalytic coupling membrane catalyst, ASP/CM (PANI-encapsulated aluminum silicate/ceramic membrane), was prepared using inexpensive silicate and polyaniline as the base materials, with in situ polymerization combined with co-focus magnetron sputtering. Under optimal conditions (25 mA/cm², 10 mM Na₂SO₄, 1.0 mL·min^-1 flow rate, and 50 μM 4-CP concentration), the membrane achieved about 95.1% removal of 4-CP and the degradation rate after five cycles was higher than 85%. In addition, O₂^•- and •OH are important active species in the electrocatalytic degradation of 4-CP. The 4-CP electrocatalytic membrane filtration process is a dual process of cathode reduction dechlorination and anodic oxidation. This work offers new insights into developing next-generation electrocatalytic membranes and expands the practical applications of electrocatalytic filtration systems.