过渡金属催化氨基羰基化反应。

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical record Pub Date : 2025-05-08 DOI:10.1002/tcr.202500029

Fatemeh Doraghi, Mohammad Hossein Morshedsolouk, Niki Raisi, Tolou Hosseinifar, Milad Noori, Bagher Larijani, Mohammad Mahdavi

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引用次数: 0

摘要

过渡金属催化的氨基羰基化反应以低成本、易获得的CO气体为C1基，以胺为亲核试剂，被广泛用于制备酰胺类化合物，酰胺类化合物广泛存在于生物活性药物、天然产物和聚合物中。这类反应也被用于构建各种具有生物活性的杂环。在这篇综述中，我们重点介绍了过去十年来在各种过渡金属催化体系（钯、铑、钌、铱、铁、铜和钴）下涉及胺和CO的氨基羰基化反应。

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Transition Metal-Catalyzed Aminocarbonylation Reactions.

Transition-metal-catalyzed aminocarbonylation reactions using low-cost and accessible CO gas as a C1 building block and amine as a nucleophile have been widely used to prepare amides, which are broadly exist in bioactive drugs, natural products, and polymers. This type of reaction has also been applied to construct various biologically active heterocycles. In this review, we highlight aminocarbonylation reactions involving amine and CO under various transition metal catalysis systems (palladium, rhodium, ruthenium, iridium, iron, copper, and cobalt) over the past decade.

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来源期刊

Chemical record 化学-化学综合

CiteScore

11.00

自引率

3.00%

发文量

188

审稿时长

>12 weeks

期刊介绍： The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.