水合物饱和度和基质渗透率变化共定渗流能力对含游离气水合物储层降压共生气的影响

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-04-25 eCollection Date: 2025-05-06 DOI:10.1021/acsomega.5c00118
Liang Zhao, Zhiqiang Fan, Peng Li, Kun He, Dayong Wang
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引用次数: 0

摘要

在水合物储层内,如果其整体渗流能力有利于压力传播,则下伏游离气层的降压可以促进有效的天然气联产。这种整体渗流能力是由水合物饱和度(S H)和岩石基质渗透率(k)共同决定的,并且在不同的水合物储层中甚至在同一储层的不同位置都是不同的。在这项研究中,我们设计了一种实验/模拟相结合的方法来研究不同水合物饱和度和岩石基质渗透率共同确定的整体渗流能力对降压天然气联产的影响。实验表明,在中等饱和度条件下(S H = 0.19),低基质渗透率条件下(k = 1.5 mD),气产速率在初始阶段快速上升,随后逐渐下降直至稳定。采用精心设定参数的热-水-化学耦合模型预测结果与实验测量结果吻合较好。模拟整个反应器内压力和S - H的时空演化表明,压力优先在游离气层中传播,然后逐渐垂直向上传播到上覆含水层,导致水合物缓慢解离。因此,初期快速产气主要以游离气产气为主,而低速产气阶段则由水合物解离控制。将初始S - H提高到较高水平(0.40)只会进一步抑制含水层内的压力传播,而不会显著降低峰值产气量。相比之下,将k值提高到中等水平(25 mD)可以显著提高整个储层的压力,使峰值产气量提高数倍。然而,在这种情况下,水合物的快速解离导致储层潜热的过度消耗,从而降低了持续解离的动力,最终制约了后续低速率产气阶段产气速率的提高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of the Codetermined Seepage Ability by Varying Hydrate Saturation and Rock-Matrix Permeability on Depressurized Gas Coproduction in Hydrate Reservoir with an Underlying Free-Gas Layer.

Within hydrate reservoir, depressurization in the underlying free-gas layer could facilitate efficient gas coproduction, provided that its overall seepage ability is conducive to pressure propagation. Such overall seepage ability is codetermined by hydrate saturation (S H) and rock-matrix permeability (k), and varies across different hydrate reservoirs and even at different locations of the same reservoir. In this study, we designed an experiment/simulation integrated approach to investigate the effect of the codetermined overall seepage ability by varying hydrate saturation and rock-matrix permeability on depressurized gas coproduction. The experiment reveals that under the conditions of moderate saturation (S H = 0.19) and low rock-matrix permeability (k = 1.5 mD), gas coproduction rate initially increased quickly, followed by a gradual decrease until eventual stabilization. The prediction results of a coupled Thermo-Hydro-Chemical model with carefully specified parameters can match well with the experimental measurements. The simulated spatiotemporal evolution of pressure and S H in the whole reactor demonstrates that pressure propagates preferentially in the free-gas layer, and then gradually propagates vertically upward into the overlying hydrate-bearing layer, causing slow hydrate dissociation. Thus, the initial rapid gas production is mainly dominated by free gas production, while the low-rate gas production stage is controlled by hydrate dissociation. Raising the initial S H to a high level (0.40) only further suppresses the pressure propagation within the hydrate-bearing layer, without significantly reducing the peak gas production rate. Comparatively, increasing the k to a moderate level (25 mD) significantly facilitates pressure throughout the reservoir, causing a several-fold increase in the peak gas production rate. However, in this case, the rapid hydrate dissociation results in excessive consumption of the reservoir's latent heat, thereby reducing the driving force for sustained dissociation and ultimately constraining the increase in the gas production rate during the subsequent low-rate gas production stage.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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