Reductive Catalytic Fractionation of Lignocellulosic Biomass: The Impact of Impurities in Catalyst.

Catalytic fractionation of lignocellulosic biomass is a promising technology for obtaining different fractions and the valorization of lignin. Reductive catalytic fractionation (RCF) is one of these technologies in which catalysts play an essential role. In this work, the impact of impurities in catalysts on the output of RCF is investigated. It is found that the yield of phenolic monomers is almost not influenced by the residual chloride (Cl) ions in the commercially available Ru/C catalyst. However, the presence of Cl ions in the catalyst facilitated hemicellulose removal and delignification. Moreover, the enzymatic conversion rate of cellulose in the solid residue increases after RCF, attributed to the enhanced removal of lignin and hemicellulose in the presence of Cl ions. The impact of Cl ions can be eliminated by removing the Cl ions in the catalyst. This work provides an engineering perspective for upscaling RCF technology using large-scale synthesized catalysts.