巨光学双折射MOF结构各向异性的共配体调谐。

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-05-14 DOI:10.1039/d5cc01224d

Svyatoslav A. Povarov , Ekaterina D. Iukhnevich , Pavel V. Alekseevskiy , Dmitry I. Pavlov , Andrei S. Potapov , Irina D. Yushina , Valentin A. Milichko , Alena N. Kulakova

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引用次数: 0

摘要

通过调整金属有机骨架的共配体组成来控制其结构各向异性，从而提高其双折射性能。合成了一组具有三个共配体和H4TCPB的基于cd的mof。实验揭示了MOF结构各向异性和双折射的演化规律，在可见光谱范围内，MOF结构各向异性和双折射的实验最大值Δn = 0.223，理论最大值Δn = 0.58。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Co-ligand tuning of MOF structural anisotropy for giant optical birefringence†

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Co-ligand tuning of MOF structural anisotropy for giant optical birefringence†

The control of the structural anisotropy of metal–organic frameworks (MOFs) by tuning their co-ligand composition to enhance the birefringence properties is demonstrated. A set of Cd-based MOFs with three co-ligands and H₄TCPB were synthesised. We experimentally revealed the evolution of the MOF structural anisotropy and birefringence, which was equal to maximal Δn = 0.223 in experiments and Δn = 0.58 in theory within the visible spectral range.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.