氨基甲酸酯和二硫代烯基硅配合物。

IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-03-19 eCollection Date: 2025-04-14 DOI:10.1021/acs.organomet.5c00038

Yuzhong Wang, John C Johnson, Kayla G Palmer, Pingrong Wei, Earle R Adams, Mitchell E Lahm, Henry F Schaefer, Gregory H Robinson

{"title":"氨基甲酸酯和二硫代烯基硅配合物。","authors":"Yuzhong Wang, John C Johnson, Kayla G Palmer, Pingrong Wei, Earle R Adams, Mitchell E Lahm, Henry F Schaefer, Gregory H Robinson","doi":"10.1021/acs.organomet.5c00038","DOIUrl":null,"url":null,"abstract":"Reactions of the amidinato-silylene chloride PhC( t BuN)2SiCl (1) with imidazole-based dithione dimer 2, lithium dithiolene radical 3, and dithiolate dimer 4 result in the synthesis of a series of silicon complexes 5-7, respectively, containing both amidinato and dithiolene ligands. 7 is the first structurally characterized silicon(II) dithiolene complex. The structural and bonding characteristics of 5-7 have been probed by both experimental and theoretical methods.","PeriodicalId":56,"journal":{"name":"Organometallics","volume":"44 7","pages":"802-806"},"PeriodicalIF":2.5000,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12001252/pdf/","citationCount":"0","resultStr":"{\"title\":\"Amidinate- and Dithiolene-Based Silicon Complexes.\",\"authors\":\"Yuzhong Wang, John C Johnson, Kayla G Palmer, Pingrong Wei, Earle R Adams, Mitchell E Lahm, Henry F Schaefer, Gregory H Robinson\",\"doi\":\"10.1021/acs.organomet.5c00038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reactions of the amidinato-silylene chloride PhC( t BuN)2SiCl (1) with imidazole-based dithione dimer 2, lithium dithiolene radical 3, and dithiolate dimer 4 result in the synthesis of a series of silicon complexes 5-7, respectively, containing both amidinato and dithiolene ligands. 7 is the first structurally characterized silicon(II) dithiolene complex. The structural and bonding characteristics of 5-7 have been probed by both experimental and theoretical methods.\",\"PeriodicalId\":56,\"journal\":{\"name\":\"Organometallics\",\"volume\":\"44 7\",\"pages\":\"802-806\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2025-03-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12001252/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organometallics\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.organomet.5c00038\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/4/14 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organometallics","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.organomet.5c00038","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/4/14 0:00:00","PubModel":"eCollection","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

脒基-硅基氯化物PhC(t BuN)2SiCl(1)与咪唑基二硫酮二聚体2、二硫烯锂自由基3和二硫酯二聚体4反应，分别合成了一系列含有脒基和二硫烯配体的硅配合物5-7。7是第一个结构表征的硅（II）二噻吩配合物。通过实验和理论方法探讨了5-7的结构和键合特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Amidinate- and Dithiolene-Based Silicon Complexes.

Reactions of the amidinato-silylene chloride PhC( ^t BuN)₂SiCl (1) with imidazole-based dithione dimer 2, lithium dithiolene radical 3, and dithiolate dimer 4 result in the synthesis of a series of silicon complexes 5-7, respectively, containing both amidinato and dithiolene ligands. 7 is the first structurally characterized silicon(II) dithiolene complex. The structural and bonding characteristics of 5-7 have been probed by both experimental and theoretical methods.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.