Dennis Reinhard, Sven M. Elbert, Wen-Shan Zhang, Frank Rominger, Rasmus R. Schröder, Michael Mastalerz
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引用次数: 0
摘要
封面特征说明了蝴蝶形状的V2Dy2配位团簇配合物对外部磁场中微波辐射的响应。在他们的研究文章（DOI: 202500011）中，J. Arneth， J. Braun, a . K. Powell， R. Klingeler和来自海德堡和卡尔斯鲁厄研究小组的同事们报告了一个新的蝴蝶复合物家族，它将现有的蝴蝶库扩展到使用VIII离子。利用联合磁化和多频高场EPR研究系统地研究了磁耦合的性质，揭示了单离子各向异性和3d-4f交换的强烈相互作用。
Dead Ends and Detours Towards a Rigid Hexasalicylic Aldehyde Precursor for Triptycene-Based Porous Materials
The Cover Feature illustrates the response of a butterfly-shaped V2Dy2 coordination cluster complex to microwave radiation in an external magnetic field. In their Research Article (DOI: 202500011), J. Arneth, J. Braun, A. K. Powell, R. Klingeler and co-workers from groups in Heidelberg and Karlsruhe report a new family of butterfly complexes that extend the existing library of butterflies towards using VIII ions. A systematic investigation of the nature of magnetic coupling using combined magnetisation and multifrequency high-field EPR studies revealed a strong interplay of single ion anisotropy and 3d-4f exchange.
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