区域选择性和非对映选择性合成吲哚喹啉-噻唑烷-2-硫酮和双吲哚喹啉-二氨基二硫酸衍生物，并研究其光致发光性质和潜在应用

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2025-05-12 DOI:10.1016/j.tet.2025.134708

Leila Kavoosi, Bagher Aghamiri, F. Matloubi Moghaddam

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引用次数: 0

摘要

本研究提出了一种区域选择性和非对构选择性合成吲哚喹啉-噻唑烷-2-硫酮和双吲哚喹啉-二氨基二硫代化合物的方法。目标化合物是通过二硫化碳、各种胺和2-（11h -吲哚[1,2-b]喹啉-11-酰基）-1-苯基比1- 1衍生物的一锅反应合成的。反应在温和条件下进行，产物收率高，选择性好。该方案操作简单，并已在克尺度上进行了验证，表明其适合大规模合成和化合物库生成。此外，合成的杂化物表现出光致发光的特性，这可能是进一步跨学科研究的兴趣。

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Regio- and diastereoselective synthesis of indeno-quinoxaline-thiazolidine-2-thione and bis-indeno-quinoxaline-dicarbamodithioate derivatives, along with an investigation of their photoluminescent properties and potential applications

This study presents a regio- and diastereoselective method for synthesizing indeno-quinoxaline-thiazolidine-2-thione and bis-indeno-quinoxaline-dicarbamodithioate hybrids. The target compounds are synthesized via a one-pot reaction of carbon disulfide, various amines, and 2-(11H-indeno [1,2-b]quinoxalin-11-ylidene)-1-phenylethan-1-one derivatives. The reaction proceeds under mild conditions, affording the products in high yields with high selectivity. The protocol is operationally simple and has been demonstrated on a gram scale, indicating its suitability for large-scale synthesis and compound library generation. Additionally, the synthesized hybrids exhibit photoluminescent properties, which may be of interest for further interdisciplinary investigation.

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来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.