煅烧温度对原子/分子层沉积无机/有机杂化陶瓷纳滤膜理化性能的影响

IF 2.9 Q1 MATERIALS SCIENCE, CERAMICS

Open Ceramics Pub Date : 2025-05-12 DOI:10.1016/j.oceram.2025.100795

M.P. Nijboer , H. Sondhi , E. Makhoul , M. Bechelany , S. Gabrielli , F. Roozeboom , A. Nijmeijer , A.Y. Kovalgin , M.W.J. Luiten-Olieman

{"title":"煅烧温度对原子/分子层沉积无机/有机杂化陶瓷纳滤膜理化性能的影响","authors":"M.P. Nijboer , H. Sondhi , E. Makhoul , M. Bechelany , S. Gabrielli , F. Roozeboom , A. Nijmeijer , A.Y. Kovalgin , M.W.J. Luiten-Olieman","doi":"10.1016/j.oceram.2025.100795","DOIUrl":null,"url":null,"abstract":"<div><div>Post-deposition calcination in the air of hybrid inorganic/organic layers is considered to remove the organic constituents and completely create a full inorganic membrane. This study aims to investigate to what extent such a removal occurs and the effect of remaining organic constituents on the physicochemical properties of the membrane layer.</div><div>Three hybrid layers were deposited using trimethylaluminum, two aliphatic- (ethylene glycol and 1,6-hexanediol) and one aromatic alcohol (hydroquinone). The effects of the different calcination treatments on the physicochemical properties were investigated. Differential thermogravimetric analysis established that the maximum mass loss rate temperatures for the hybrid layers grown from the aliphatic alcohols are lower than those from the aromatic co-reactant. After 250 °C, water contact angles (WCAs) were between 46° - 92° and IR spectroscopy and XPS showed the presence of carbon. Calcination at 350 °C reduced the WCA to 0° - 25° and decreased carbon content.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"22 ","pages":"Article 100795"},"PeriodicalIF":2.9000,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes\",\"authors\":\"M.P. Nijboer , H. Sondhi , E. Makhoul , M. Bechelany , S. Gabrielli , F. Roozeboom , A. Nijmeijer , A.Y. Kovalgin , M.W.J. Luiten-Olieman\",\"doi\":\"10.1016/j.oceram.2025.100795\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Post-deposition calcination in the air of hybrid inorganic/organic layers is considered to remove the organic constituents and completely create a full inorganic membrane. This study aims to investigate to what extent such a removal occurs and the effect of remaining organic constituents on the physicochemical properties of the membrane layer.</div><div>Three hybrid layers were deposited using trimethylaluminum, two aliphatic- (ethylene glycol and 1,6-hexanediol) and one aromatic alcohol (hydroquinone). The effects of the different calcination treatments on the physicochemical properties were investigated. Differential thermogravimetric analysis established that the maximum mass loss rate temperatures for the hybrid layers grown from the aliphatic alcohols are lower than those from the aromatic co-reactant. After 250 °C, water contact angles (WCAs) were between 46° - 92° and IR spectroscopy and XPS showed the presence of carbon. Calcination at 350 °C reduced the WCA to 0° - 25° and decreased carbon content.</div></div>\",\"PeriodicalId\":34140,\"journal\":{\"name\":\"Open Ceramics\",\"volume\":\"22 \",\"pages\":\"Article 100795\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2025-05-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Open Ceramics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666539525000628\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Open Ceramics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666539525000628","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}

引用次数: 0

摘要

混合无机/有机层沉积后在空气中煅烧被认为可以去除有机成分并完全形成完整的无机膜。本研究旨在探讨这种去除的程度以及剩余有机成分对膜层物理化学性质的影响。用三甲基铝、两个脂肪族（乙二醇和1,6-己二醇）和一个芳香醇（对苯二酚）沉积了三个杂化层。考察了不同焙烧处理对其理化性质的影响。差热重分析表明，由脂肪醇生长的杂化层的最大失重温度低于由芳香族共反应物生长的杂化层的最大失重温度。250°C后，水接触角（WCAs）在46°~ 92°之间，红外光谱和XPS显示碳的存在。在350°C下煅烧，WCA降至0°- 25°，碳含量降低。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes

查看原文本刊更多论文

Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes

Post-deposition calcination in the air of hybrid inorganic/organic layers is considered to remove the organic constituents and completely create a full inorganic membrane. This study aims to investigate to what extent such a removal occurs and the effect of remaining organic constituents on the physicochemical properties of the membrane layer.

Three hybrid layers were deposited using trimethylaluminum, two aliphatic- (ethylene glycol and 1,6-hexanediol) and one aromatic alcohol (hydroquinone). The effects of the different calcination treatments on the physicochemical properties were investigated. Differential thermogravimetric analysis established that the maximum mass loss rate temperatures for the hybrid layers grown from the aliphatic alcohols are lower than those from the aromatic co-reactant. After 250 °C, water contact angles (WCAs) were between 46° - 92° and IR spectroscopy and XPS showed the presence of carbon. Calcination at 350 °C reduced the WCA to 0° - 25° and decreased carbon content.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊