{"title":"高速卷绕制备超高分子量聚乙烯高渗透中空纤维膜","authors":"Jianguo Xu, Wenpeng Fan, Yong Qi","doi":"10.1002/app.57032","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Membrane aeration technology, as a critical means to improve water treatment efficiency, has garnered significant attention in the fields of international water treatment, environmental protection, and membrane science. While enhancing the aeration membrane flux can improve oxygen transfer efficiency, such improvements often negatively impact the mechanical properties and durability of the membrane. To address this challenge, high-strength and durable ultra-high molecular weight polyethylene (UHMWPE) hollow fiber membranes were fabricated in this study using thermally induced phase separation (TIPS) at varying spinning winding speeds. Microscopic imaging revealed that the UHMWPE hollow fiber membranes exhibit a loose network-like microporous structure internally and a dense surface layer. Furthermore, the microporous structure became more pronounced with increasing winding speed. At a winding speed of 9 m min<sup>−1</sup>, the membrane achieved a maximum gas flux of 1797 L m<sup>−2</sup> min<sup>−1</sup>. The maximum tensile strength of the membrane was 3.8 MPa, and the maximum elongation at break was 420%, demonstrating that the membrane retained excellent mechanical properties and durability even under elevated gas flux conditions. This high-performance aeration membrane is well suited for diverse water treatment applications. Moreover, this study showed that optimizing winding speed can efficiently reconcile the conflict between increasing the flux and maintaining mechanical properties.</p>\n </div>","PeriodicalId":183,"journal":{"name":"Journal of Applied Polymer Science","volume":"142 24","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of UHMWPE Hollow Fiber Membrane With High Permeability Using High Winding Speed\",\"authors\":\"Jianguo Xu, Wenpeng Fan, Yong Qi\",\"doi\":\"10.1002/app.57032\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>Membrane aeration technology, as a critical means to improve water treatment efficiency, has garnered significant attention in the fields of international water treatment, environmental protection, and membrane science. While enhancing the aeration membrane flux can improve oxygen transfer efficiency, such improvements often negatively impact the mechanical properties and durability of the membrane. To address this challenge, high-strength and durable ultra-high molecular weight polyethylene (UHMWPE) hollow fiber membranes were fabricated in this study using thermally induced phase separation (TIPS) at varying spinning winding speeds. Microscopic imaging revealed that the UHMWPE hollow fiber membranes exhibit a loose network-like microporous structure internally and a dense surface layer. Furthermore, the microporous structure became more pronounced with increasing winding speed. At a winding speed of 9 m min<sup>−1</sup>, the membrane achieved a maximum gas flux of 1797 L m<sup>−2</sup> min<sup>−1</sup>. The maximum tensile strength of the membrane was 3.8 MPa, and the maximum elongation at break was 420%, demonstrating that the membrane retained excellent mechanical properties and durability even under elevated gas flux conditions. This high-performance aeration membrane is well suited for diverse water treatment applications. Moreover, this study showed that optimizing winding speed can efficiently reconcile the conflict between increasing the flux and maintaining mechanical properties.</p>\\n </div>\",\"PeriodicalId\":183,\"journal\":{\"name\":\"Journal of Applied Polymer Science\",\"volume\":\"142 24\",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2025-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Polymer Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/app.57032\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/app.57032","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
摘要
膜曝气技术作为提高水处理效率的重要手段,在国际水处理、环境保护、膜科学等领域受到了广泛关注。虽然提高曝气膜通量可以提高氧传递效率,但这种提高往往会对膜的力学性能和耐久性产生负面影响。为了解决这一挑战,本研究采用热诱导相分离(TIPS)技术在不同的纺丝缠绕速度下制备了高强度和耐用的超高分子量聚乙烯(UHMWPE)中空纤维膜。显微成像结果表明,超高分子量聚乙烯中空纤维膜内部呈松散的网状微孔结构,表层致密。随着卷绕速度的增加,微孔结构更加明显。在9 m min−1的卷绕速度下,膜的最大气体通量为1797 L m−2 min−1。膜的最大拉伸强度为3.8 MPa,最大断裂伸长率为420%,表明膜在高气体通量条件下仍保持良好的力学性能和耐久性。这种高性能曝气膜非常适合各种水处理应用。此外,研究表明,优化绕线速度可以有效地解决增加助熔剂与保持机械性能之间的矛盾。
Preparation of UHMWPE Hollow Fiber Membrane With High Permeability Using High Winding Speed
Membrane aeration technology, as a critical means to improve water treatment efficiency, has garnered significant attention in the fields of international water treatment, environmental protection, and membrane science. While enhancing the aeration membrane flux can improve oxygen transfer efficiency, such improvements often negatively impact the mechanical properties and durability of the membrane. To address this challenge, high-strength and durable ultra-high molecular weight polyethylene (UHMWPE) hollow fiber membranes were fabricated in this study using thermally induced phase separation (TIPS) at varying spinning winding speeds. Microscopic imaging revealed that the UHMWPE hollow fiber membranes exhibit a loose network-like microporous structure internally and a dense surface layer. Furthermore, the microporous structure became more pronounced with increasing winding speed. At a winding speed of 9 m min−1, the membrane achieved a maximum gas flux of 1797 L m−2 min−1. The maximum tensile strength of the membrane was 3.8 MPa, and the maximum elongation at break was 420%, demonstrating that the membrane retained excellent mechanical properties and durability even under elevated gas flux conditions. This high-performance aeration membrane is well suited for diverse water treatment applications. Moreover, this study showed that optimizing winding speed can efficiently reconcile the conflict between increasing the flux and maintaining mechanical properties.
期刊介绍:
The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.