高速卷绕制备超高分子量聚乙烯高渗透中空纤维膜

IF 2.7 3区 化学 Q2 POLYMER SCIENCE
Jianguo Xu, Wenpeng Fan, Yong Qi
{"title":"高速卷绕制备超高分子量聚乙烯高渗透中空纤维膜","authors":"Jianguo Xu,&nbsp;Wenpeng Fan,&nbsp;Yong Qi","doi":"10.1002/app.57032","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Membrane aeration technology, as a critical means to improve water treatment efficiency, has garnered significant attention in the fields of international water treatment, environmental protection, and membrane science. While enhancing the aeration membrane flux can improve oxygen transfer efficiency, such improvements often negatively impact the mechanical properties and durability of the membrane. To address this challenge, high-strength and durable ultra-high molecular weight polyethylene (UHMWPE) hollow fiber membranes were fabricated in this study using thermally induced phase separation (TIPS) at varying spinning winding speeds. Microscopic imaging revealed that the UHMWPE hollow fiber membranes exhibit a loose network-like microporous structure internally and a dense surface layer. Furthermore, the microporous structure became more pronounced with increasing winding speed. At a winding speed of 9 m min<sup>−1</sup>, the membrane achieved a maximum gas flux of 1797 L m<sup>−2</sup> min<sup>−1</sup>. The maximum tensile strength of the membrane was 3.8 MPa, and the maximum elongation at break was 420%, demonstrating that the membrane retained excellent mechanical properties and durability even under elevated gas flux conditions. This high-performance aeration membrane is well suited for diverse water treatment applications. Moreover, this study showed that optimizing winding speed can efficiently reconcile the conflict between increasing the flux and maintaining mechanical properties.</p>\n </div>","PeriodicalId":183,"journal":{"name":"Journal of Applied Polymer Science","volume":"142 24","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of UHMWPE Hollow Fiber Membrane With High Permeability Using High Winding Speed\",\"authors\":\"Jianguo Xu,&nbsp;Wenpeng Fan,&nbsp;Yong Qi\",\"doi\":\"10.1002/app.57032\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>Membrane aeration technology, as a critical means to improve water treatment efficiency, has garnered significant attention in the fields of international water treatment, environmental protection, and membrane science. While enhancing the aeration membrane flux can improve oxygen transfer efficiency, such improvements often negatively impact the mechanical properties and durability of the membrane. To address this challenge, high-strength and durable ultra-high molecular weight polyethylene (UHMWPE) hollow fiber membranes were fabricated in this study using thermally induced phase separation (TIPS) at varying spinning winding speeds. Microscopic imaging revealed that the UHMWPE hollow fiber membranes exhibit a loose network-like microporous structure internally and a dense surface layer. Furthermore, the microporous structure became more pronounced with increasing winding speed. At a winding speed of 9 m min<sup>−1</sup>, the membrane achieved a maximum gas flux of 1797 L m<sup>−2</sup> min<sup>−1</sup>. The maximum tensile strength of the membrane was 3.8 MPa, and the maximum elongation at break was 420%, demonstrating that the membrane retained excellent mechanical properties and durability even under elevated gas flux conditions. This high-performance aeration membrane is well suited for diverse water treatment applications. Moreover, this study showed that optimizing winding speed can efficiently reconcile the conflict between increasing the flux and maintaining mechanical properties.</p>\\n </div>\",\"PeriodicalId\":183,\"journal\":{\"name\":\"Journal of Applied Polymer Science\",\"volume\":\"142 24\",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2025-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Polymer Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/app.57032\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/app.57032","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

摘要

膜曝气技术作为提高水处理效率的重要手段,在国际水处理、环境保护、膜科学等领域受到了广泛关注。虽然提高曝气膜通量可以提高氧传递效率,但这种提高往往会对膜的力学性能和耐久性产生负面影响。为了解决这一挑战,本研究采用热诱导相分离(TIPS)技术在不同的纺丝缠绕速度下制备了高强度和耐用的超高分子量聚乙烯(UHMWPE)中空纤维膜。显微成像结果表明,超高分子量聚乙烯中空纤维膜内部呈松散的网状微孔结构,表层致密。随着卷绕速度的增加,微孔结构更加明显。在9 m min−1的卷绕速度下,膜的最大气体通量为1797 L m−2 min−1。膜的最大拉伸强度为3.8 MPa,最大断裂伸长率为420%,表明膜在高气体通量条件下仍保持良好的力学性能和耐久性。这种高性能曝气膜非常适合各种水处理应用。此外,研究表明,优化绕线速度可以有效地解决增加助熔剂与保持机械性能之间的矛盾。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of UHMWPE Hollow Fiber Membrane With High Permeability Using High Winding Speed

Membrane aeration technology, as a critical means to improve water treatment efficiency, has garnered significant attention in the fields of international water treatment, environmental protection, and membrane science. While enhancing the aeration membrane flux can improve oxygen transfer efficiency, such improvements often negatively impact the mechanical properties and durability of the membrane. To address this challenge, high-strength and durable ultra-high molecular weight polyethylene (UHMWPE) hollow fiber membranes were fabricated in this study using thermally induced phase separation (TIPS) at varying spinning winding speeds. Microscopic imaging revealed that the UHMWPE hollow fiber membranes exhibit a loose network-like microporous structure internally and a dense surface layer. Furthermore, the microporous structure became more pronounced with increasing winding speed. At a winding speed of 9 m min−1, the membrane achieved a maximum gas flux of 1797 L m−2 min−1. The maximum tensile strength of the membrane was 3.8 MPa, and the maximum elongation at break was 420%, demonstrating that the membrane retained excellent mechanical properties and durability even under elevated gas flux conditions. This high-performance aeration membrane is well suited for diverse water treatment applications. Moreover, this study showed that optimizing winding speed can efficiently reconcile the conflict between increasing the flux and maintaining mechanical properties.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信