冷冻CFCl3基质中甲酸甲酯自由基阳离子的光化学反应

IF 0.7 Q4 CHEMISTRY, MULTIDISCIPLINARY

Moscow University Chemistry Bulletin Pub Date : 2025-05-13 DOI:10.3103/S0027131425700026

M. Ya. Melnikov, O. I. Gromov, V. I. Pergushov, D. A. Pomogailo, I. D. Sorokin

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引用次数: 0

摘要

已经发现了甲酸甲酯自由基阳离子（RCs）光转化的新机制，其中甲基中的氢原子在热诱导1,2转移到桥接氧原子上的RC经过光诱导H+转移到基体上。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photochemistry of Methyl Formate Radical Cations in Frozen CFCl3 Matrices

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Photochemistry of Methyl Formate Radical Cations in Frozen CFCl3 Matrices

A novel mechanism has been discovered for the phototransformations of methyl formate radical cations (RCs) wherein an RC that is furnished upon thermally induced 1,2-transfer of an hydrogen atom in the methyl group to the bridging oxygen atom undergoes photoinduced H⁺ transfer to the matrix.

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来源期刊

Moscow University Chemistry Bulletin CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.30

自引率

14.30%

发文量

期刊介绍： Moscow University Chemistry Bulletin is a journal that publishes review articles, original research articles, and short communications on various areas of basic and applied research in chemistry, including medical chemistry and pharmacology.