黄铜基板上电沉积碳纤维增强CoNi涂层的性能研究

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY
Juan Xue, Linjia Zhang
{"title":"黄铜基板上电沉积碳纤维增强CoNi涂层的性能研究","authors":"Juan Xue,&nbsp;Linjia Zhang","doi":"10.1016/j.ijoes.2025.101053","DOIUrl":null,"url":null,"abstract":"<div><div>Carbon fiber is added to the CoNi plating solution to prepare the carbon fiber-reinforced CoNi coating. The influence of carbon fiber on the surface morphology, chemical composition, corrosion resistance, wear resistance and magnetic performance of the CoNi electrodeposited coating is investigated. Carbon fibers have good electrical conductivity and act as additional nucleation sites during electrodeposition, leading to an enhanced of CoNi deposition rate. The carbon fiber-reinforced CoNi coating shows smaller and finer nodular structures and is composed of 61.4 % cobalt, 25.5 % nickel and 13.1 % carbon. The addition of carbon fiber to the plating solution increases the cobalt content while decreasing the amount of nickel in the CoNi coating. Compared with the CoNi coating, the carbon fiber-reinforced CoNi coating exhibits better corrosion resistance with the most positive corrosion potential (-0.511 V) and the lowest corrosion current density (9.07 μA/cm<sup>2</sup>). The presence of carbon fiber hinders grain growth, leading to a finer, more compact grain structure, which results in higher wear resistance. Moreover, according to the magnetic hysteresis loop of the CoNi coating, the saturation magnetization of CoNi is about 83.2 emu/g while the saturation magnetization of carbon fiber-reinforced CoNi coating is approximtely 92.5 emu/g. The coercivity of the carbon fiber-reinforced CoNi coating is 468.9 Oe, which is twice as large as that of the CoNi coating.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 8","pages":"Article 101053"},"PeriodicalIF":1.3000,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of the performance of carbon fiber-reinforced CoNi coatings electrodeposited on brass substrates\",\"authors\":\"Juan Xue,&nbsp;Linjia Zhang\",\"doi\":\"10.1016/j.ijoes.2025.101053\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Carbon fiber is added to the CoNi plating solution to prepare the carbon fiber-reinforced CoNi coating. The influence of carbon fiber on the surface morphology, chemical composition, corrosion resistance, wear resistance and magnetic performance of the CoNi electrodeposited coating is investigated. Carbon fibers have good electrical conductivity and act as additional nucleation sites during electrodeposition, leading to an enhanced of CoNi deposition rate. The carbon fiber-reinforced CoNi coating shows smaller and finer nodular structures and is composed of 61.4 % cobalt, 25.5 % nickel and 13.1 % carbon. The addition of carbon fiber to the plating solution increases the cobalt content while decreasing the amount of nickel in the CoNi coating. Compared with the CoNi coating, the carbon fiber-reinforced CoNi coating exhibits better corrosion resistance with the most positive corrosion potential (-0.511 V) and the lowest corrosion current density (9.07 μA/cm<sup>2</sup>). The presence of carbon fiber hinders grain growth, leading to a finer, more compact grain structure, which results in higher wear resistance. Moreover, according to the magnetic hysteresis loop of the CoNi coating, the saturation magnetization of CoNi is about 83.2 emu/g while the saturation magnetization of carbon fiber-reinforced CoNi coating is approximtely 92.5 emu/g. The coercivity of the carbon fiber-reinforced CoNi coating is 468.9 Oe, which is twice as large as that of the CoNi coating.</div></div>\",\"PeriodicalId\":13872,\"journal\":{\"name\":\"International Journal of Electrochemical Science\",\"volume\":\"20 8\",\"pages\":\"Article 101053\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2025-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Electrochemical Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1452398125001282\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Electrochemical Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1452398125001282","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0

摘要

将碳纤维加入到CoNi镀液中,制备碳纤维增强CoNi涂层。研究了碳纤维对CoNi镀层表面形貌、化学成分、耐蚀性、耐磨性和磁性能的影响。碳纤维具有良好的导电性,在电沉积过程中作为额外的成核位点,导致CoNi沉积速率的提高。碳纤维增强的CoNi涂层呈现出更小、更精细的球状结构,由61.4 %钴、25.5 %镍和13. %碳组成。在镀液中加入碳纤维可以提高镀层的钴含量,同时降低镀层中镍的含量。与CoNi涂层相比,碳纤维增强的CoNi涂层具有更好的耐蚀性,腐蚀电位最高(-0.511 V),腐蚀电流密度最低(9.07 μA/cm2)。碳纤维的存在阻碍了晶粒的生长,导致更细、更致密的晶粒结构,从而产生更高的耐磨性。此外,根据CoNi涂层的磁滞回线可知,CoNi的饱和磁化强度约为83.2 emu/g,而碳纤维增强CoNi涂层的饱和磁化强度约为92.5 emu/g。碳纤维增强CoNi涂层的矫顽力为468.9 Oe,是普通CoNi涂层的2倍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of the performance of carbon fiber-reinforced CoNi coatings electrodeposited on brass substrates
Carbon fiber is added to the CoNi plating solution to prepare the carbon fiber-reinforced CoNi coating. The influence of carbon fiber on the surface morphology, chemical composition, corrosion resistance, wear resistance and magnetic performance of the CoNi electrodeposited coating is investigated. Carbon fibers have good electrical conductivity and act as additional nucleation sites during electrodeposition, leading to an enhanced of CoNi deposition rate. The carbon fiber-reinforced CoNi coating shows smaller and finer nodular structures and is composed of 61.4 % cobalt, 25.5 % nickel and 13.1 % carbon. The addition of carbon fiber to the plating solution increases the cobalt content while decreasing the amount of nickel in the CoNi coating. Compared with the CoNi coating, the carbon fiber-reinforced CoNi coating exhibits better corrosion resistance with the most positive corrosion potential (-0.511 V) and the lowest corrosion current density (9.07 μA/cm2). The presence of carbon fiber hinders grain growth, leading to a finer, more compact grain structure, which results in higher wear resistance. Moreover, according to the magnetic hysteresis loop of the CoNi coating, the saturation magnetization of CoNi is about 83.2 emu/g while the saturation magnetization of carbon fiber-reinforced CoNi coating is approximtely 92.5 emu/g. The coercivity of the carbon fiber-reinforced CoNi coating is 468.9 Oe, which is twice as large as that of the CoNi coating.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信